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煤的分级萃取与组成
引用本文:刘长城,陈红,孙元宝,王晓华,曹景沛,魏贤勇.煤的分级萃取与组成[J].吉林大学学报(理学版),2004,42(3):442-446.
作者姓名:刘长城  陈红  孙元宝  王晓华  曹景沛  魏贤勇
作者单位:中国矿业大学化工学院应用化学系,徐州,221008;中国人民解放军空军后勤学院科研部,徐州,221000;中国矿业大学化工学院应用化学系,徐州,221008
基金项目:国家自然科学基金(批准号:29676045),国家重点基础研究发展规划基金(批准号:1999022101),高等学校博士学科点专项科研基金(批准号:98029016),煤炭普通高校跨世纪学术带头人培养计划基金,黑龙江省科技厅攻关项目基金(批准号:20020109007).
摘    要:对6种煤进行分级萃取, 按PBM法与NIST谱库化合物质谱数据进行计算机检索对照, 根据置信度或相似度, 并辅之以GC/FTIR数据确定化合物的结构. 检测出多种生物标志物,揭示了煤分子结构的复杂性, 实验结果表明, 随着煤化作用加深, 煤样中缩合程度加大.

关 键 词:煤液化  煤结构  芳烃
文章编号:1671-5489(2004)03-0442-05
收稿时间:2003-10-15
修稿时间:2003年10月15

Fractionated extraction and composition of coal
LIU Chang-cheng.Fractionated extraction and composition of coal[J].Journal of Jilin University: Sci Ed,2004,42(3):442-446.
Authors:LIU Chang-cheng
Institution:1. Department of Application Chemistry, School of Chemical Engineering, China University of Mining Technology, Xuzhou 221008, China; 2. Research and Development Section, Air Force Logistics College of PLA, Xuzhou 221000, China
Abstract:The present paper deals with the extracts from six raw coals and they were indexed according to the NIST database by PBM method, then their molecular configurations were confirmed via GC/FTIR. Many biomakers have been found in the extracts, which suggests that the configuration of coal molecules are very complicated; the compress degree of the coal increases along with the coalization.
Keywords:coal liquefaction  configuration of coal molecule  aromatics
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