N,N-二甲基苯甲醛连氮及其Cu(I)配合物的合成与表征 |
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引用本文: | 裘灵光,田玉鹏.N,N-二甲基苯甲醛连氮及其Cu(I)配合物的合成与表征[J].安徽大学学报(自然科学版),2003,27(2):80-84. |
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作者姓名: | 裘灵光 田玉鹏 |
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作者单位: | 安徽大学,化学化工学院,安徽,合肥,230039 |
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基金项目: | 国家自然科学基金;29871001; |
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摘 要: | 设计合成了一种新的连氮类D-π-D型化合物N,N-二甲基苯甲醛连氮(L1),制备了其双核Cu(I)的配合物,分别用元素分析、红外光谱、核磁共振、电子自旋共振波谱、质谱及电喷雾质谱等进行了表征,并对它们的荧光性质进行了初步研究。
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关 键 词: | 连氮类化合物 D-π-D型化合物 Cu(I)配合物 |
文章编号: | 1000-2162(2003)02-0080-05 |
Synthesis and characterization of N,N-dimethylbenzalazine and its Cu(I) complex |
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Abstract: | In this paper,a new azine compound,N-dimethylbenzalazine and its Cu(I) complex were designed and synthesized,and characterized by element analysis,IR,1HNMR,ESR,MS and FAB-MS. Structure and fluorescent spectra of ligand L1 and complex Cu2L13(ClO4)2 were studied. The result shows that the kind of the ligand and its copper (I) complex are likely to exhibit third-order nonlinear optical activity. |
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Keywords: | azine compound D-π-D compound Cu(I) complex |
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