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连续PET生产过程的数学模型
引用本文:曹柳林,吕南斗.连续PET生产过程的数学模型[J].系统仿真学报,2001,13(4):536-538,545.
作者姓名:曹柳林  吕南斗
作者单位:北京化工大学自动化系,
摘    要:介绍一个工业化聚酯(PET)生产过程的数学模型,其中包括酯交换模型、予缩聚和终缩聚模型。模型从聚合反应机理出发,考虑了所有的主反应和主要的副反应,以实测的工艺操作参数为输入,以各反应釜的分子量分布参数为输出。文章讨论了操作参数对产品分子量分布的影响,模型仿真结果与现场运行结果证明了模型的有效性。

关 键 词:聚合反应  聚酯  数学模型  分子量分布  PET  生产过程
文章编号:1004-731(2001)04-0536-03

Modeling of Continuous PET Process
CAO Liu-lin,LV Nan-dou.Modeling of Continuous PET Process[J].Journal of System Simulation,2001,13(4):536-538,545.
Authors:CAO Liu-lin  LV Nan-dou
Abstract:A mathematical model of continuous PET process is developed, in which transesterfication model, prepolymerization and finishing polymerization model are involved. Based on the polymerization mechanism, the model describes all main reactions and major side reactions with measurable operating variables as input and parameters of MWD in every reactor as output. Effects of operating conditions on MWD are studied, and effectiveness of the model has been proved through the simulation and on-site application.
Keywords:polymerization  polyethylene terephthalate  mathematical model  MWD
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