| 2,3-双芳亚氨基-1,4-二硫杂环己烷EIMS谱特征 |
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| 引用本文： | 刘玮炜,李娜,唐丽娟,赵跃强,胡宏纹. 2,3-双芳亚氨基-1,4-二硫杂环己烷EIMS谱特征[J]. 华侨大学学报(自然科学版), 2007, 28(4): 390-393 |
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| 作者姓名： | 刘玮炜 李娜 唐丽娟 赵跃强 胡宏纹 |
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| 作者单位： | 淮海工学院,化学工程系,江苏,连云港,222005;南京大学,化学系,江苏,南京,210093 |
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| 基金项目： | 国家自然科学基金资助项目(20072016)，江苏省教育厅自然科学基金资助项目(03KJB150009)，淮海工学院学科建设基金资助项目(XK01009) |
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| 摘 要： | 利用硫原子上的烷基化反应,合成出5个2,3-双芳基亚氨基-1,4-二硫杂环己烷类化合物,由元素分析、红外光谱分析(IR)1、H核磁共振谱分析(1H NMR)、质谱分析(MS)初步确定化合物的结构,并以单晶X射线衍射分析对其结构进一步确证.研究这5个化合物的电子轰击质谱(EIMS),探讨并归纳其裂解规律,总结该类化合物的EIMS谱特征.
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| 关 键 词： | 硫烷基化 2 3-双芳基亚氨基-1 4-二硫杂环己烷 电子轰击质谱 裂解 |
| 文章编号： | 1000-5013（2007）04-0390-04 |
| 修稿时间： | 2007-04-11 |
The Spectroscopy Characteristics of EIMS of 2,3-Biarylimino-1, 4-Dithiacyclohexane |
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| LIU Wei-wei,LI Na,TANG Li-juan,ZHAO Yue-qiang,HU Hong-wen. The Spectroscopy Characteristics of EIMS of 2,3-Biarylimino-1, 4-Dithiacyclohexane[J]. Journal of Huaqiao University(Natural Science), 2007, 28(4): 390-393 |
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| Authors: | LIU Wei-wei LI Na TANG Li-juan ZHAO Yue-qiang HU Hong-wen |
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| Affiliation: | 1. Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China; 2. Department of Chemistry, Nanjing University, Nanjing 210093, China |
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| Abstract: | Five compounds of 2,3-biarylimino-1,4-dithiacyclohexane were prepared by S-alkylation,the structure of them were analyzed by elemental analysis,IR(infrared),1H NMR(nuclear magnetic resonance) and MS(mass spectrometry) preliminarily,and further confirmed by X-ray diffraction.The 1H NMR,EIMS(electron impact mass spectrometry) specta of 2,3-biarylimino-1,4-dithiacyclohexane were studied in detail.The possible fragmentation mechanism for these compounds was proposed,and the EIMS characteristics of the title compounds have been summarized systematically. |
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| Keywords: | S-alkylation 2 3-biarylimino-1 4-dithiacyclohexane EIMS fragmentation |
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