| TiO2-Fe3+/Ti复合电极的制备及电化学特性研究 |
| |
| 引用本文： | 胡敏,苏桂琴,汪琪,董宗木. TiO2-Fe3+/Ti复合电极的制备及电化学特性研究[J]. 广西大学学报(自然科学版), 2006, 31(1): 20-23 |
| |
| 作者姓名： | 胡敏 苏桂琴 汪琪 董宗木 |
| |
| 作者单位： | 安徽师范大学,化学生物系,安徽,芜湖,241008 |
| |
| 基金项目： | 安徽省教育厅自然科学基金 |
| |
| 摘 要： | 用F e3 掺杂的二氧化钛溶胶制得钛基纳米T iO2-F e3 /T i复合催化电极,用紫外分光光度法和XRD表征了电极材料吸收光谱特性和电极表面的微观结构,用循环伏安法研究了电极的电化学特性.结果表明,由于F e3 的存在,在-0.78 V(vs.SCE)处出现了一个还原峰,表明电极表面膜中存在F e3 还原成F e2 并进一步与电极中T iO2发生化学反应,是EC过程.
|
| 关 键 词： | TiO2-Fe3 /Ti电极 制备 特性 苯酚 |
| 文章编号： | 1001-7445(2006)01-0020-04 |
| 收稿时间： | 2005-09-28 |
| 修稿时间： | 2005-12-29 |
The preparation of the TiO2-Fe3+/Ti compound electrode and the research of E-chemical specific |
| |
| HU Min,SU Gui-qin,WANG Qi,DONG Zong-mu. The preparation of the TiO2-Fe3+/Ti compound electrode and the research of E-chemical specific[J]. Journal of Guangxi University(Natural Science Edition), 2006, 31(1): 20-23 |
| |
| Authors: | HU Min SU Gui-qin WANG Qi DONG Zong-mu |
| |
| Affiliation: | Department of Chemistry and Biology, Anhui Normal University, Wuhu 241008 ,China |
| |
| Abstract: | The precursor Ti(OE_t)_4 was prepared by anodic dissolution of metallic titanium in absolution ethanol and directly hydrolyzed to prepare nanocrystalline TiO_2 film with Fe~(3 ) doping in it on titanium electrode(TiO_2-Fe~(3 )/Ti) by a sol-gel process.UV-Vis and XRD were used to sign the microcosmic structure of nanocrystalline TiO_2 film with Fe~(3 ) doping in it.Electric catalysis activities of the TiO_2-Fe~(3 )/Ti electrode were investigated by cyclic voltammetry.The investigation reveals that there is a redox peak on-0.78 V(vs.SCE),that is to say,Fe(OH)_3 has been reduced to Fe(OH)_2.It is EC process. |
| |
| Keywords: | TiO_2-Fe~(3 )/Ti electrode specific property phenol |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
