| Eu(NA)_3Phen的合成及发光性能研究 |
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| 引用本文： | 刘德文,赵宇,吴爱萍. Eu(NA)_3Phen的合成及发光性能研究[J]. 北京工商大学学报(自然科学版), 1998, 0(3) |
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| 作者姓名： | 刘德文 赵宇 吴爱萍 |
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| 作者单位： | 北京轻工业学院化学工程系!北京100037 |
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| 摘 要： | 在乙醇体系中合成了三价稀土金属离子Eu~3＋与烟酰基丙酮（简称NA）、邻菲罗啉（Phen）的三元配合物．对配合物进行了元素分析，测定了激发光谱、发射光谱、热谱和红外光谱．结果表明：该配合物的组成为Eu（NA）_3·phen，热稳定性较好．三元配合物发射的荧光强度大于二元配合物的荧光强度．
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| 关 键 词： | 铕（皿）的络合物 烟酰基丙酮 邻菲罗啉 |
A STUDY OF THE SYNTHESES AND LUMINESCENCE PROPERTIES OF Eu(NA)_3Phen |
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| Liu Dewen, Zhao Yangyu, Wu Aiping. A STUDY OF THE SYNTHESES AND LUMINESCENCE PROPERTIES OF Eu(NA)_3Phen[J]. Journal of Beijing Technology and Business University:Natural Science Edition, 1998, 0(3) |
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| Authors: | Liu Dewen Zhao Yangyu Wu Aiping |
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| Abstract: | The complexes of Eu (Ⅲ) with mixed nicotinic acetone and phenanthroline was synthesized. Some characters of the complexes were determined by using elemental analysis, IR spectra, DTA-TG analysis and excitation and emission spectra. The results show that chemical composition is Eu (NA)_3 phen, and the fluorescent intensity of ternary complexes is six times higher than that of binary complexes. |
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| Keywords: | Eu(Ⅲ) complexes nicotinic acetone phenanthroline luminescence properties |
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