| 脯胺酰胺衍生物的合成及在催化不对称aldol反应的应用 |
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| 引用本文： | 熊亚平.脯胺酰胺衍生物的合成及在催化不对称aldol反应的应用[J].科学技术与工程,2011,11(5). |
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| 作者姓名： | 熊亚平 |
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| 作者单位： | 同济大学化学系,上海,200092 |
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| 摘 要： | 以天然氨基酸为原料合成了一种脯胺酰胺衍生物,并研究了它在催化芳香醛与丙酮的不对称羟醛缩合反应中的应用。酸的添加能够提高反应速率及产物的对应选择性。
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| 关 键 词： | 脯胺酰胺 不对称 aldol反应 乙酸 |
| 收稿时间： | 12/1/2010 4:24:33 PM |
| 修稿时间： | 12/1/2010 4:24:33 PM |
Synthesis of prolinamide and its application in asymmetric aldol reaction |
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| Xiong Ya-ping.Synthesis of prolinamide and its application in asymmetric aldol reaction[J].Science Technology and Engineering,2011,11(5). |
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| Authors: | Xiong Ya-ping |
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| Institution: | XIONG Ya-ping,JIN Yun-zhou,DAI Jin-ling(Department of Chemistry,Tongji University,Shanghai 200092,P.R.China) |
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| Abstract: | Prolinamide was synthesized from natural amino acids,which has been used as a catalyst in the asymmetric aldol condensation reaction between aromatic aldehyde and acetone.The addition of acid can obviously enhance the reaction rate and enantioselectivity. |
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| Keywords: | prolinamide asymmetry aldol reaction acetic acid |
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