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渐消递推滤波辅助光谱分析:最佳自适应算法
引用本文:李志良,余般梅.渐消递推滤波辅助光谱分析:最佳自适应算法[J].应用科学学报,1994,12(2):150-158.
作者姓名:李志良  余般梅
作者单位:湖南大学四达应用化学研究所,国防科学技术大学,湖南大学,中科院化学冶金研究所
基金项目:国家开放实验室与自然科学基金及四达应用化学研究所基金
摘    要:研究了Kalman渐消递推最佳滤波辅助光谱辨析。基于Kalman滤波达到最优时其新息序列互不相关的性质,提出了一种新的渐消滤波─—最佳自适应算法。通过在线自适应地调整遗忘因子从而使滤波(器)在存在模型误差或受到外扰时仍保持收敛性和最优性。用于重叠峰的辨识,能取得更好效果。

关 键 词:渐消递推滤波  自适应算法  光谱分析

FADING RECURSIVE FILTERING AIDED SPECTROSCOPY An Optimal Adaptive Algorithm
LI ZHILIANG YU BANMEI.FADING RECURSIVE FILTERING AIDED SPECTROSCOPY An Optimal Adaptive Algorithm[J].Journal of Applied Sciences,1994,12(2):150-158.
Authors:LI ZHILIANG YU BANMEI
Institution:LI ZHILIANG YU BANMEI(Hunan University)(Changsha Institute(STAR Institute of Applied Chemistry)of Technology)QIAN FENG SHI LEMING PAN ZHONGXIAO(Hunan University)(Chemical Metallurgy Institute)NIE SHENGZHE(ST AR Institute of Applied Chemistry)
Abstract:The fading Kalman recursive optimal filtering is studied for spectroscopicresolution,Based on the nature of Kalman filter that the residual sequenees arenot correlated when the optimal gain is obtained, a new fading filtering-optimaladaptive algorithm is proposed and utilized. Through the on-line and adaptiveadjustment of the fading or forgetting factor,the convergency and optimality ofKalman filtering are improved using measured outputs or estimated results, evenwhen there exist model errors and/or when the system is affected by unmeasurableexternal disturbances.The algorithm developed is applied to overlapped peakresolution with good results.
Keywords:fading recursive filtering  Kalman filter  optimal adaptive algorithm  chemometrics  spectroscopic resolution  multicompo- nent analysis    
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