新型中温离子导体复合膜:Sn_(0.94)Sc_(0.06)P_2O_7和聚四氟乙烯(PTFE)

采用固相法合成中温离子导体Sn0.94Sc0.06P2O7和聚四氟乙烯(PTFE)的复合膜,并进行XRD,SEM及DSCTGA测试表征.用电化学工作站研究了复合膜在75~225℃下的导电特性.SEM分析结果表明复合膜具有良好的微观结构,XRD分析结果表明复合膜已形成了单相的SnP2O7立方相结构.气体气氛对复合膜电导率有显著的影响,σ(dry air)#σ(wet air)#σ(wet H2).该复合膜在湿润H2气氛中150℃下,电导率达到最大值6.5×10-4 S·cm-1.

Intermediate Temperature Ionic Conducting Composite Membrane:Sn0.94Sc0.06P2O7 and Polytetrafluoroethylene (PTFE)

An intermediate temperature ionic conducting composite membrane,Sn_0.94Sc_0.06P₂O₇ and polytetrafluoroethylene (PTFE),was prepared by solid-state reaction method.The obtained composite membrane was characterized by XRD,SEM and DSC-TGA.The conductivities of composite membrane was investigated by using electrochemical workstation at the range of 75~225 ℃.The microstructure indicated that the composite membrane was well-crystallized and very compact.XRD pattern indicated that the composite membrane exhibited a single cubic phase structure of SnP2O7.The experimental atmosphere remarkably influenced the conductivity in the orderσ(dry air)<σ(wet air)<σ(wet H2).The highest conductivity was observed to be 6.5×10^-4 S·cm^-1 for the composite membrane under wet H2 atmosphere at 150 ℃.