| Study on an Organic Hybrid Made from Chlorinated Polyethylene and 2,2''''-methylene-bis- (4-methyl-6-cyclohexylphenol) |
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| 引用本文： | 刘继涛,李玮茹,俞建勇,王善元. Study on an Organic Hybrid Made from Chlorinated Polyethylene and 2,2''''-methylene-bis- (4-methyl-6-cyclohexylphenol)[J]. 东华大学学报(英文版), 2003, 20(2) |
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| 作者姓名： | 刘继涛 李玮茹 俞建勇 王善元 |
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| 作者单位： | Textile College，Donghua University，Shanghai 200051，Textile College，Donghua University，Shanghai 200051，Textile College，Donghua University，Shanghai 200051，Textile College，Donghua University，Shanghai 200051 |
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| 摘 要： | The dynamic mechanical properties and miscibility of an organic hybrid made from chlorinated polyethylene (CPE) and 2, 2'-methyIene-bis-( 4-methyl-6-cyclohexylphenol) ( ZKF ) are mainly discussed in this paper. It is found that ZKF acts as an antiplasticizer in CPE matrix and has good miscibility even with large ratio in CPE /ZKF hybrids. The glass transition temperature of various CPE /ZKF hybrids determined by DSC give a good fit to Wood's equation. Bifunctional ZKF is supposed to improve the intermolecular force of CPE, and the improvement is developed when the ZKF content increases. On the other hand, the viscoelastic properties are highly improved with the addition of ZKF. TA and tanδ peak values increase when the ZKF content increase in the CPE /ZKF hybrids, the damping capacity has been improved during the glass transition of CPE /ZKF hybrids. In addition, the glass transition temperature shifts to room temperature from the low temperature with the continuous addition of ZKF to CPE.
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Study on an Organic Hybrid Made from Chlorinated Polyethylene and 2,2''''-methylene-bis-(4-methyl-6-cyclohexylphenol) |
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| LIU Ji-tao LI Wei-ru YU Jian-yong WANG Shan-yuan Textile College,Donghua University,Shanghai. Study on an Organic Hybrid Made from Chlorinated Polyethylene and 2,2''''-methylene-bis-(4-methyl-6-cyclohexylphenol)[J]. Journal of Donghua University, 2003, 20(2) |
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| Authors: | LIU Ji-tao LI Wei-ru YU Jian-yong WANG Shan-yuan Textile College Donghua University Shanghai |
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| Affiliation: | Textile College, Donghua University, Shanghai 200051 |
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| Abstract: | The dynamic mechanical properties and miscibility of an organic hybrid made from chlorinated polyethylene (CPE) and 2, 2'-methylene-bis-(4-methyl-6-cyclohexylphenol) (ZKF) are mainly discussed in this paper. It is found that ZKF acts as an antiplasticizer in CPE matrix and has good miscibility even with large ratio in CPE /ZKF hybrids. The glass transition temperature of various CPE/ZKF hybrids determined by DSC give a good fit to Wood's equation. Bifunctional ZKF is supposed to improve the intermolecular force of CPE, and the improvement is developed when the ZKF content increases. On the other hand, the viscoelastic properties are highly improved with the addition of ZKF. TA and tanδ peak values increase when the ZKF content increase in the CPE /ZKF hybrids, the damping capacity has been improved during the glass transition of CPE /ZKF hybrids. In addition, the glass transition temperature shifts to room temperature from the low temperature with the continuous addition of ZKF to CPE. |
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| Keywords: | CPE hybrid viscoelastic damping glass transition antiplasticizer |
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