| 基于Baeyer-Villiger反应与Wittig反应合成几种新型苯并螺环酮类化合物 |
| |
| 引用本文： | 吴运凯,裴维兵,王宇超,刘宇. 基于Baeyer-Villiger反应与Wittig反应合成几种新型苯并螺环酮类化合物[J]. 吉林大学学报(理学版), 2002, 57(5): 1261-1266 |
| |
| 作者姓名： | 吴运凯 裴维兵 王宇超 刘宇 |
| |
| 作者单位： | 长春工业大学 化学与生命科学院, 材料科学高等研究院, 长春 130012 |
| |
| 摘 要： | 对Pd2(dba)3参与邻溴苯基环丁酮类化合物开环反应得到的苯并螺环二酮类化合物进行衍生化研究, 并通过Baeyer-Villiger反应和Wittig反应考察一系列含有不同官能团的反应底物. 结果表明, 该方法可高选择性地制备不同类型的苯并螺环化合物.
|
| 关 键 词： | 苯并螺环化合物 Baeyer Villiger氧化 Wittig反应 |
| 收稿时间： | 2018-11-30 |
Synthesis of Several New Benzospirone Compounds Based on Baeyer Villiger Reaction and Wittig Reaction |
| |
| WU Yunkai,PEI Weibing,WANG Yuchao,LIU Yu. Synthesis of Several New Benzospirone Compounds Based on Baeyer Villiger Reaction and Wittig Reaction[J]. Journal of Jilin University: Sci Ed, 2002, 57(5): 1261-1266 |
| |
| Authors: | WU Yunkai PEI Weibing WANG Yuchao LIU Yu |
| |
| Affiliation: | Advanced Insitute of Materials Science, College of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China
|
| |
| Abstract: | The derivatization of benzosriprodiones obtained from Pd2(dba)3 participated ring opening reaction of O bromophenylcyclobutanone derivatives was studied, a series of substrates containing different functional groups were investigated by Baeyer Villiger reaction and Wittigreaction. The results show that different types of benzospirocyclic compoundscan be prepared by the proposed method with high selectivity. |
| |
| Keywords: | benzospirocyclic compound Baeyer Villiger oxidation Wittig reaction |
|
| 点击此处可从《吉林大学学报(理学版)》浏览原始摘要信息 |
|
点击此处可从《吉林大学学报(理学版)》下载全文 |
