| 重铬酸吡啶盐作用下烯丙基甾醇的氧化反应研究 |
| |
| 引用本文： | 崔建国,黄燕敏,曾陇梅.重铬酸吡啶盐作用下烯丙基甾醇的氧化反应研究[J].广西科学,2001,8(4):281-283. |
| |
| 作者姓名： | 崔建国 黄燕敏 曾陇梅 |
| |
| 作者单位： | 广西师范学院化学系南宁市明秀东路530001 |
| |
| 基金项目： | 广东省自然科学基金 ( 970 15 4) |
| |
| 摘 要： | 在不同的反应条件下，用重铬酸吡啶盐（PDC）氧化豆甾醇，分别得到以豆甾-4，22-二烯-6β-羟基-3-酮或豆甾-4，22-二烯-3，6-二酮为主的产物。结果与有关文献的报道有所不同。
|
| 关 键 词： | 烯丙基甾醇 重铬酸吡啶盐 豆甾－4 22－二烯－6β－羟基－3－酮 氧化反应 豆甾－4 22－二烯－3 6－二酮 |
| 收稿时间： | 2001/6/7 0:00:00 |
| 修稿时间： | 2001/8/13 0:00:00 |
Novel Oxidation of Homoallylic Sterols with Pyridinium Dichromate |
| |
| Cui Jianguo,Huang Yanmin and Zeng Longmei.Novel Oxidation of Homoallylic Sterols with Pyridinium Dichromate[J].Guangxi Sciences,2001,8(4):281-283. |
| |
| Authors: | Cui Jianguo Huang Yanmin and Zeng Longmei |
| |
| Institution: | Dept of Chem, Guangxi Teachers College, East Mingxiulu, Nanning, Guangxi, 530001, China,Dept of Chem, Guangxi Teachers College, East Mingxiulu, Nanning, Guangxi, 530001, China and Dept of Chem, Guangxi Teachers College, East Mingxiulu, Nanning, Guangxi, 530001, China |
| |
| Abstract: | Stigmasterol was oxidized with pyridinium dichromate. Stigmast-4, 22-dien-6β-ol-3-one and stigmast-4, 22-dien-3, 6-dione were obtained as main product separately in different reactive conditions. The result was different from the report in the related literature. |
| |
| Keywords: | homoallylic sterols pyridinium dichromate ( PDC ) stigmast-4 22-dien-6β-ol-3-one stigmast-4 22-dien-3 6-dione |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《广西科学》浏览原始摘要信息 |
| 点击此处可从《广西科学》下载免费的PDF全文 |
|
