| C60与乙醇胺或茂钠加成反应产物的电喷雾电离质谱研究 |
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| 引用本文： | 杨高升,魏先文.C60与乙醇胺或茂钠加成反应产物的电喷雾电离质谱研究[J].安徽师范大学学报(自然科学版),2000,23(2):129-130. |
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| 作者姓名： | 杨高升 魏先文 |
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| 作者单位： | 安徽师范大学化学与材料科学学院,安徽,芜湖,241000 |
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| 摘 要： | 用电喷雾电离质谱研究Ｃ６０与乙醇胺或茂钠的加成反应产物，结果表明：Ｃ６０与乙醇胺或茂钠的加成产物用通式表示为Ｃ６０Ｒｎ及少量含氧物质Ｃ６０ＲｎＯｍ，其中单加合物Ｃ６０Ｒ（Ｒ：ＮＨ２ＣＨ２ＣＨ２ＯＨ、Ｃｐ）的优势产物。
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| 关 键 词： | 加成反应 电喷雾电离质谱 碳60 乙醇胺 茂钠 |
STUDY ON THE PRODUCTS OF C60 ADDITION WITH HYDROXYETHYLAMINE OR CYCLOPENTADIENYL SODIUM BY ELECTROSPRAY IONIZATION MASS SPECTROSCOPY |
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| YANG Gao-sheng,WEI Xian-wen.STUDY ON THE PRODUCTS OF C60 ADDITION WITH HYDROXYETHYLAMINE OR CYCLOPENTADIENYL SODIUM BY ELECTROSPRAY IONIZATION MASS SPECTROSCOPY[J].Journal of Anhui Normal University(Natural Science Edition),2000,23(2):129-130. |
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| Authors: | YANG Gao-sheng WEI Xian-wen |
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| Abstract: | The addition reactions of C 60 with hydroxyethylamine or cyclopentadienyl sodium were reported. The reaction products were determied directly by ESI MS without pre ionization. The results indicate that the main products were monoadducts and there are some C 60 R n and minor C 60 R nO m(R=NH 2CH 2CN 2OH,Cp) in the products. |
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| Keywords: | C_(60) chemistry addition reaction electrospray-ionization mass spectroscopy |
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