| 取代环戊二烯基负离子的呋喃甲酰化反应 |
| |
| 引用本文： | 马玉道,刘桂宏,焦纶基,王琳.取代环戊二烯基负离子的呋喃甲酰化反应[J].山东大学学报(理学版),1996(1). |
| |
| 作者姓名： | 马玉道 刘桂宏 焦纶基 王琳 |
| |
| 作者单位： | Dept. of Chem.，Shandong Univ.，Jinan |
| |
| 摘 要： | ６，６－二烷基富烯和有机锂、有机镁试剂反应可以得到叔碳取代的环戊二烯基负离子，该负离子与２－呋喃甲酰氯或５－溴代－２－呋喃甲酰氯反应，得到呋喃甲酰基取代的富烯化合物。通过１ＨＮＭＲ、ＩＲ和元素分析确定了新化合物的结构
|
| 关 键 词： | 2－呋喃甲酰化 6.6－二烷基富烯 有机锂 合成 |
FUROYLATION OF SUBSTITUTED CYCLOPENTADIENYL ANION |
| |
| Ma Yudao, Liu Guihong,Jiao Lunji,Wang Lin.FUROYLATION OF SUBSTITUTED CYCLOPENTADIENYL ANION[J].Journal of Shandong University,1996(1). |
| |
| Authors: | Ma Yudao Liu Guihong Jiao Lunji Wang Lin |
| |
| Abstract: | The 6, 6-dialkylfulvene reacts with organolithium, organomagnesium reagents to give tert-alkyl substituted cyclopentadienyl anion. The anion reacts with 2-furoyl chloride or 5-bromo-2-furoyl chloride to yield the furoyl substituted fulvene. On the basis of H NMR,IR and elemental analysis, their structures were determined. |
| |
| Keywords: | furoylation 6 6-dialkylfulvene organolithium synthesis |
| 本文献已被 CNKI 等数据库收录！ |
