Ferroelectric phase transition in relaxor ferroelectric single crystals 0.76PMN-0.24PT |
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Authors: | Guisheng Xu Haosu Luo Pingchu Wang Zhenyi Qi Zhiwen Yin |
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Institution: | (1) Laboratory of Functional Inorganic Materials, Shanghai Institue of Ceramics, Chinese Academy of Sciences, 201800 Shanghai, China;(2) Xiangtan Polytechnic University, 411201 Xianglan, China |
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Abstract: | The features of the single crystals 0.76PMN-0.24PT in dietectric, ferroetectric, pyroetectric properties and domain structures
indicate that they are located between typical ferroetectrics and normal ones. The unpoled crystals present a transitional
domain configuration between microdomains and typical macrodomains while the crystals on (001) cuts undergo fietd-induced
phase transition under poling, showing two special temperature points Td andT
m during the succedent heating procedure. The dietectric constant starts to decrease drastically at Td during cooling, or the transformation from induced macrodomain to transitional domain takes place atT
d during heating. Ferroetectric-paraetectric phase transition or depolarization continues within the whole temperature range
ofT
d-T
m, where ferroetectric phase in the form of transitional macrodomains coexists with paraetectric phase. Then the crystals macroscopically
transoform into paraetectric phase containing ferroetectric microdomains at a temperature aboveT
m. However, owing to the influence of crystallite orientation on fietd-induced phase transition, the temperatureT
d does not appear in the same temperature-etectric fietd history in multicrystal ceramics with the same composition as the
above single crystals. |
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Keywords: | retaxor ferroetectrics single crystals ferroetectric phase transition domain structure PMNT |
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