| [Ru(bpy)2(dmbpy)]PF6Cl的合成方法及性质分析 |
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| 引用本文： | 徐红柳,陈奋,刘学.[Ru(bpy)2(dmbpy)]PF6Cl的合成方法及性质分析[J].佛山科学技术学院学报(自然科学版),2006,24(2):70-72. |
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| 作者姓名： | 徐红柳 陈奋 刘学 |
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| 作者单位： | 汕头大学,化学系,广东,汕头,515063;汕头大学,化学系,广东,汕头,515063;汕头大学,化学系,广东,汕头,515063 |
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| 摘 要： | 介绍了R u的有关bpy配合物的合成和性质,给出了手性试剂在亚砜条件下R u的bpy配合物的合成,通过圆二色谱仪、紫外-可见分光光度计、X-R ay衍射仪及电化学仪器研究该配合物的性质,讨论了R u的bpy配合物的结构和电化学等特性。
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| 关 键 词： | Ru配合物 2 2’-联吡啶 晶体结构 |
| 文章编号： | 1008-0171（2006）02-0070-03 |
| 收稿时间： | 2006-02-04 |
| 修稿时间： | 2006-02-04 |
The synthetic way and character analysis of Chiral reagent Ruthenium (II) complexes |
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| XU Hong-liu,CHEN Fen,LIU Xue.The synthetic way and character analysis of Chiral reagent Ruthenium (II) complexes[J].Journal of Foshan University(Natural Science Edition),2006,24(2):70-72. |
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| Authors: | XU Hong-liu CHEN Fen LIU Xue |
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| Institution: | Department of Applied Chemistry, Shantou University, Shantou 515063, China |
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| Abstract: | Ru(bpy)_2Cl_2] is converted to Ru(bpy)_2(Me_2SO)Cl]Cl,it can be synthesized by DMSO,Ru(bpy)_2Cl_2].The ligand centered bands of CD spectra are at ca.450 nm and the MLCT bands at ca.450 nm.In this way,the synthesis of ruthenium tris(bpy) complexes with almost complete stereorentention at the metal centre was done.The complex that displays lyotropic liquid crystalline behaviour Photophysical properties was investigated.The complex shows a good lum inescense property with a high quantum yield. |
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| Keywords: | ruthenium(II) complex bpy crystal structure |
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