| 淤浆鼓泡床中Raney镍催化加氢反应的过程动力学 |
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| 引用本文： | 陈荣富,顾其威. 淤浆鼓泡床中Raney镍催化加氢反应的过程动力学[J]. 华东理工大学学报(自然科学版), 1988, 0(3) |
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| 作者姓名： | 陈荣富 顾其威 |
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| 作者单位： | 华东化工学院联合化学反应工程研究所(陈荣富)，华东化工学院联合化学反应工程研究所(顾其威) |
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| 摘 要： | 以Raney镍为催化剂,在淤浆鼓泡床中进行丁炔二醇加氢合成丁二醇这一两步串联加氢反应。探讨了在实验条件下气液传质、液-固传质和颗粒表面反应的相对阻力,从而用定量对比法确证反应属动力学控制。其本征速率方程可用幂函数或Langmuir-Hinshelwood模型表达。前者适用于宏观过程对比;后者适用于本征机理研究,并可对液相反应物级数的变化作出满意的解释。
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| 关 键 词： | 加氢反应 金属催化剂 动力学分析 淤浆鼓泡床 Raney镍催化剂 过程动力学 丁炔二醇 丁烯二醇 丁二醉 |
Process kinetics of hydrogenation reaction with Raney nickel catalyst in bubbling slurry bed |
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| Chert Rongfu and Gu Qiwei. Process kinetics of hydrogenation reaction with Raney nickel catalyst in bubbling slurry bed[J]. Journal of East China University of Science and Technology, 1988, 0(3) |
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| Authors: | Chert Rongfu and Gu Qiwei |
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| Abstract: | With Raney nickel as catalyst, the two steps hydrogenation reaction of 1,4-butynediol to 1, 4-butanediol carries out in bubbling slurry bed. The relative resistances of gas-liquid masstransfer, liquid-solid mass transfer and pellet surface reaction are determined under experimental conditions, thus the surface reaction rate controlling can be predicted by this quantitative method.Both intrinsic rate equations of two steps can be expressed as power model or/and Langmuir-Hinshelwood model. The former is more favorable for correlation with transport process, while the latter benefits for reaction mechanism studies, and also the variations of reaction order of both liquid reactants have been explained rather successfully. |
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| Keywords: | hydrogenation reaction metal catalyst kinetics analysis bubbling slurry bed Raney nickel catalyst process kinetics 1 4-butynediol 1 4-butenediol 1 4-butanediol |
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