| 阴离子法丁羟胶合成中“假凝胶”的研究 |
| |
| 引用本文： | 李立朝,张兴英,韩丙勇.阴离子法丁羟胶合成中“假凝胶”的研究[J].北京化工大学学报(自然科学版),2003,30(5):44-47. |
| |
| 作者姓名： | 李立朝 张兴英 韩丙勇 |
| |
| 作者单位： | 北京化工大学新型高分子材料的制备与加工北京市重点实验室,北京,100029 |
| |
| 摘 要： | 采用阴离子聚合法、双锂引发剂、环己烷为溶剂 ,合成双端丁羟胶 (HTPB)。研究了合成中出现的“假凝胶”现象及解缔剂YB对丁羟胶分子量及分子量分布、官能度、聚合反应速率的影响 ,得到了较为满意的结果。
|
| 关 键 词： | 丁羟胶 解缔剂 官能度 丁羟胶 解缔剂 官能度 |
| 修稿时间： | 2002年12月13日 |
On pseudo-gel in synthesis of HTPB by anionic polymerization |
| |
| LI Li-chao,ZHANG Xing-ying,HAN Bing-yong.On pseudo-gel in synthesis of HTPB by anionic polymerization[J].Journal of Beijing University of Chemical Technology,2003,30(5):44-47. |
| |
| Authors: | LI Li-chao ZHANG Xing-ying HAN Bing-yong |
| |
| Institution: | The Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials; Beijing University of Chemical Technology; Beijing; China |
| |
| Abstract: | Hydroxyl-terminated polybutadiene (HTPB) was prepared by anionic polymerization using cyclohexane as solvent, and YB was used as dissociation reagent in the synthesis of HTPB. The sequent influence on the molecular distribution, average functionality and the polymerization temperature and pressure in the reactor were investigated in detail. Finally,by using YB, HTPB could be controlled, of which the molecular weight distribution was smaller than 1.3 and the average functionality was improved. |
| |
| Keywords: | hydroxyl-terminated polybutadiene (HTPB) dissociation reagent average functionality |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《北京化工大学学报(自然科学版)》浏览原始摘要信息 |
| 点击此处可从《北京化工大学学报(自然科学版)》下载免费的PDF全文 |
