| 金雀异黄酮和刺芒柄花素的合成及表征 |
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| 引用本文： | 朱百鸣,张小林.金雀异黄酮和刺芒柄花素的合成及表征[J].江西科学,2011,29(4):477-479,524. |
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| 作者姓名： | 朱百鸣 张小林 |
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| 作者单位： | 1. 江西省环保厅环境工程评估中心,江西南昌,330029
2. 南昌大学抚州医学分院,江西抚州,344000 |
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| 摘 要： | 以多羟基酚与对位取代的苯乙酸为原料,探究在BF3.Et2O作溶剂和催化剂中,天然活性物质金雀异黄酮和刺芒柄花素的合成方法及较优合成条件,结果表明金雀异黄酮不宜采用一锅法制备,刺芒柄花素在BF3.Et2O-DMF-PC l5体系用一锅法能取得较好的收率。
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| 关 键 词： | 金雀异黄酮 刺芒柄花素 一锅法 合成 |
The Synthesis and Characterization of Genistein and Formononetin |
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| ZHU Bai-ming,ZHANG Xiao-lin.The Synthesis and Characterization of Genistein and Formononetin[J].Jiangxi Science,2011,29(4):477-479,524. |
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| Authors: | ZHU Bai-ming ZHANG Xiao-lin |
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| Institution: | 1. Environment Engineering Evaluation Center of Environmental Protection Department of Jiangxi, Jiangxi Nanchang 330029 PRC; 2. Fuzhou Medical College, Nanchang University, Jiangxi Fuzhou 344000) |
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| Abstract: | The synthesis method and optimization of reaction conditions of genistein and formononetin were studied, using polyhydroxy phenol and p-substitutod phenylaeetic acid as material, BF3 · Et2O as solvent and catalyst. The result indicated that genistein is not suitable to produce by one-pot, while formononetin can be prepared in good yield in the system of BF3 · Et2O-DMF-PCl5 by one pot. |
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| Keywords: | Genistein Formononetin One-pot Synthesis |
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