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新型掺铒硼铋锶酸盐玻璃的J-O参数计算
引用本文:唐婉如,孙江亭,张家骅.新型掺铒硼铋锶酸盐玻璃的J-O参数计算[J].哈尔滨师范大学自然科学学报,2009,25(2):78-81.
作者姓名:唐婉如  孙江亭  张家骅
作者单位:1. 哈尔滨师范大学
2. 中国科学院长春光学精密机械与物理研究所
基金项目:哈尔滨市科技局创新人才研究基金项目(2006RFQXG057)
摘    要:用高温熔融法制备了成分为:B2O3-Bi2O3-SrO的新型掺铒硼铋锶酸盐玻璃.测试了样品的发射光谱和吸收光谱.利用Judd—Ofelt理论计算了该玻璃样品的J-O参数(Ω2,Ω4,Ω6)和Er^3+各相关能级的理论振子强度、实验振子强度等发光参数,并对其发光特性进行了研究.计算结果表明:该硼铋锶酸盐玻璃的共价性强于已被报道的大多数玻璃,且其跃迁几率最大的两个能级为^4I13/2和^4I15/2能级.

关 键 词:玻璃  Judd--Ofelt理论  J-O参数

J-O PARAMETERS OF NOVEL Er3+-DOPED BOROSILICATE GLASS
Tang Wanru,Sun Jiangting,Zhang Jiahua.J-O PARAMETERS OF NOVEL Er3+-DOPED BOROSILICATE GLASS[J].Natural Science Journal of Harbin Normal University,2009,25(2):78-81.
Authors:Tang Wanru  Sun Jiangting  Zhang Jiahua
Institution:Harbin Normal University;Key Laboratory of Excited State Processes;Changchun Institute of Optics;Fine Mechanics and Physics;Chinese Academy of Sciences
Abstract:In this paper,novel Er^3+ - doped B2O3 - Bi2O3 - SrO glasses were prepared by the technique of high-- temperature melting. The J - O parameters (Ω2,Ω4,Ω6), radiative transition probabilities, absorption and emission spectrometry, calculated and experimental oscillator strengths were calculated by using the theory of Judd--Ofelt. In addition,the luminescence property has been investigated. The results indicate that the covalency of this glass host is larger than many kinds of glasses which have been reported. And the best of its radiative transition probabilities is at the energy level of ^4I13/2 and ^4I15/2
Keywords:Glass  The theory of Judd-Ofelt  J-O parameters  
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