| 三聚磷酸锌铝的合成与表征 |
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| 引用本文： | 丁世文,马广成. 三聚磷酸锌铝的合成与表征[J]. 河北大学学报(自然科学版), 1992, 0(4) |
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| 作者姓名： | 丁世文 马广成 |
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| 作者单位： | 河北大学化学系(丁世文)，河北大学化学系(马广成) |
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| 摘 要： | 本文用氧化锌和氢氧化铝作为锌源和铝源,在100—400℃与磷酸反应,聚合生成了三聚磷酸锌铝。x—射线物相分析证明该产品与三聚磷酸二氢铝具有相同的结构,属同一晶系,红外光谱分析表明磷的局部对称性为正四面体,并具有部分双键特征。化学分析、DTA、TG结合x—ray分析指出,产品的化学式为AlZnP_3O_(10)·ZH_2O,该产品被加热时,于150℃左右先脱去两个结晶水,530℃分解为偏磷酸盐。初步应用试验表明,该产品作为无毒防锈颜料可以代替有毒的锌黄等,其防锈性能超过国家标准4倍。
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| 关 键 词： | 三聚磷酸盐 铝 合成 表征 |
The Synthesis and Characterization of Aluminum Zinc Thiphosphate |
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| Ding Shiwen Ma Guangcheng. The Synthesis and Characterization of Aluminum Zinc Thiphosphate[J]. Journal of Hebei University (Natural Science Edition), 1992, 0(4) |
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| Authors: | Ding Shiwen Ma Guangcheng |
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| Affiliation: | Department of chemistry |
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| Abstract: | Aluminum oxide and Zine oxide reacted with phosphoric acid at 100-150℃ for 2-3h, then aluminum zine triphosphate was obtained by polymerizing at 250-400℃ for 3-6h. Chemical analysis showed that the product has a mole ratio of ZnO:Al2O3:P2O5 = 2:l:3. x-ray diffraction and IR spectra, together with DTA and TGA studies showed that the formula of the product is AlZnP3O10· 2H2O and having a similar structure compared with A1H2P3O10· 2H2O. |
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| Keywords: | Synthesis Characterization Aluminum Zine triphosphate. |
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