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邻、间、对二甲苯与八甲基环四硅氧烷的过量摩尔体积
引用本文:欧阳钢锋,陆贵增,潘传荣,杨洋溢,黄钟奇.邻、间、对二甲苯与八甲基环四硅氧烷的过量摩尔体积[J].中山大学学报(自然科学版),2004,43(4):47-49.
作者姓名:欧阳钢锋  陆贵增  潘传荣  杨洋溢  黄钟奇
作者单位:中山大学化学与化学工程学院,广东,广州,510275
基金项目:国家重点基础研究发展计划(973计划)
摘    要:在298.15 K时用振动管密度计在全浓度范围内测量了邻、间、对二甲苯分别与八甲基环四硅氧烷(D4)组成的3个二元液体混合物的密度,并计算了此3个二元体系的过量摩尔体积VE.3个二元体系的VE均为负值,大小顺序为:间二甲苯>对二甲苯>邻二甲苯.

关 键 词:过量体积  二甲苯  八甲基环四硅氧烷
文章编号:0529-6579(2004)04-0047-03
修稿时间:2003年12月25

Excess Molar Volumes of o-,m-,p-Xylene with Octamethylcyclotetrasiloxane at 298.15 K
OUYANG Gang-feng,LU Gui-zeng,PAN Chuan-rong,YANG Yang-yi,HUANG Zhong-qi.Excess Molar Volumes of o-,m-,p-Xylene with Octamethylcyclotetrasiloxane at 298.15 K[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2004,43(4):47-49.
Authors:OUYANG Gang-feng  LU Gui-zeng  PAN Chuan-rong  YANG Yang-yi  HUANG Zhong-qi
Abstract:Densities for binary mixtures of octamethylcyclotetrasiloxane with o-xylene, m-xylene,p-xylene respectively were determined at 298.15 K, and their excess molar volumes were derived. It was showed that the excess molar volumes V~E are negative for these three binary systems, and the V~E values are in the order of m-xylene>p-xylene>o-xylene.
Keywords:excess molar volume  xylene  octamethylcyclotetrasiloxane
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