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含硼聚硅硫酸铁混凝剂成分间的相互作用
引用本文:刘小军,田宜灵,马晓鸥,康思琦,于遵宏.含硼聚硅硫酸铁混凝剂成分间的相互作用[J].华东理工大学学报(自然科学版),2001,27(6):661-665.
作者姓名:刘小军  田宜灵  马晓鸥  康思琦  于遵宏
作者单位:1. 华东理工大学洁净煤技术研究所,上海,200237
2. 天津大学化学系,天津,300072
3. 五邑大学化工系,广东,529020
摘    要:含硼聚硅硫酸铁(PFSSB)是新近开发研制成的一种性能优良的无机高分子混凝剂。本文采用化学分析和X射线衍射法研究了该混凝剂成分间的相互作用情况,考察并分析了体系的pH驰豫及电学特征。结果表明,在体系中Fe^3 有其水解聚合产物、聚硅酸、B及SO4^2-离子等之间存在相互作用。这些相互作用的存在是PFSSB稳定和混凝性能提高的重要原因。

关 键 词:混凝剂  含硼聚硅硫酸铁  相互作用  pH驰豫  电学特征  化学成分  混凝性能
文章编号:1006-3080(2001)06-0661-05
修稿时间:2000年12月29

Components' Interactions of Coagulant Polymeric Ferric Silicate-sulfate Conta ining Boron
LIU Xiao jun ,TIAN Yi ling ,MA Xiao ou ,KANG Si qi ,YU Zun hong.Components'' Interactions of Coagulant Polymeric Ferric Silicate-sulfate Conta ining Boron[J].Journal of East China University of Science and Technology,2001,27(6):661-665.
Authors:LIU Xiao jun  TIAN Yi ling  MA Xiao ou  KANG Si qi  YU Zun hong
Institution:LIU Xiao jun 1*,TIAN Yi ling 2,MA Xiao ou 3,KANG Si qi 3,YU Zun hong 1
Abstract:Polymeric ferric silicate sulfate containing boron (PFSSB) is a highly effective inorganic polymeric coagulant studied and prepared recently. The components' interactions of PFSSB were studied by chemical analysis and X ray diffraction in this paper, and the variations of pH and electrical conductivity with aging time were also investigated and analyzed. It is found that some interactions exist among Fe 3+ and its hydro polymer products, polysilicic acid, B and SO 2- 4 . These interactions of components play an important role in enhancing stability and coagulating properties of PFSSB.
Keywords:coagulant  polymeric ferric silicate  sulfate containing boron  interaction  variations of pH  electrical conductivity
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