| 微纳米卟啉金属有机络合物的合成 |
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| 引用本文： | 杨建东,黄姗.微纳米卟啉金属有机络合物的合成[J].四川大学学报(自然科学版),2016,53(1):145-151. |
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| 作者姓名： | 杨建东 黄姗 |
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| 作者单位： | 陇南师范高等专科学校生物化学系;陇南师范高等专科学校生物化学系 |
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| 基金项目： | 甘肃省自然科学基金（1308RJZK171）； 甘肃省高等学校科研项目（2013B-132）； 和校重点〖DW〗科研项目（2012LSZK01003）； 博士科研启动项目 |
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| 摘 要： | 我们通过一种简单的绿色合成方法,得到微纳米尺度的金属卟啉配合物,并通过选择不同的金属离子,实现了对金属卟啉配合物的可控组装,得到了从零位、一维和二维的金属卟啉配合物.并借助扫描电镜、红外光谱、X射线衍射谱(XRD),X射线光电子能谱(XPS)等对其结构进行了表征,详细考察了其影响纳米结构的影响因素和动力学生长过程.
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| 关 键 词： | 四羧基苯基卟啉 金属离子 微纳米结构 影响因素 |
| 收稿时间： | 2015/5/23 0:00:00 |
| 修稿时间： | 2015/6/21 0:00:00 |
Synthesis and Characterization of Micro- and Nano- Metal-porphyrin Coordination Polymer |
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| YANG Jian-Dong and HUANG Shan.Synthesis and Characterization of Micro- and Nano- Metal-porphyrin Coordination Polymer[J].Journal of Sichuan University (Natural Science Edition),2016,53(1):145-151. |
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| Authors: | YANG Jian-Dong and HUANG Shan |
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| Institution: | Department of biology & chemistry, Longnan Normal College;Department of biology & chemistry, Longnan Normal College |
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| Abstract: | Micro- and nano-scale metal-organic complexs not only have size effect, but have an adjustable assembly unit, which shows a lot of good performance. in this paper, we synthesized nanoscale mertal-porphyrin complexs by a simple and green method. by choosing the different metal ions, the different nanostructures (0D, 1D, 2D) of metal-porphyrin polymer was abtained by controlled assemble unit. its structures were characterizatized by scanning electron microscopy (SEM), infrared spectroscopy (IR), x-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), and were detailed examinated of the impact and dynamica growth of the metal-porphyrin polymer. |
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| Keywords: | Tetra carboxyphenyl porphyrin(TCPP) Metal ions Micro and nanostructures Factor |
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