| 3,4-亚甲二氧基硝基苯合成和晶体结构 |
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| 引用本文： | 冯柏成,韩德彰,吴祖望,吴作林.3,4-亚甲二氧基硝基苯合成和晶体结构[J].大连理工大学学报,2006,46(4):488-490. |
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| 作者姓名： | 冯柏成 韩德彰 吴祖望 吴作林 |
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| 作者单位： | 大连理工大学,精细化工国家重点实验室,辽宁,大连,116012;青岛科技大学,化工学院,山东,青岛,266042;青岛科技大学,化工学院,山东,青岛,266042;大连理工大学,精细化工国家重点实验室,辽宁,大连,116012 |
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| 基金项目： | Acknowledgements：The authors’ sincere thanks are expressed to Prof. Jian Fangfang for his efforts to carry out and analyze the X-ray. 0ur thanks and gratitude are also extended to Prof. Zhang Zhuangyu for his amending to the paper. |
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| 摘 要： | 3,4-亚甲二氧基硝基苯由1,2-亚甲二氧基苯经硝化反应合成. 其晶体结构经X射线衍射测定为单射晶系,空间结构P21/c,Z=4,晶包参数为a=0.378 00(8) nm; b=1.000 3(2) nm; c=1.822 4(4) nm; β=97.33(3)°; Mr=167.12; V=0.683 4(2) nm3, Dc=1.624 g/cm3, μ(MoKα)=0.136 mm-1, F(000)=344, R=0.070 7, wR=0.182 8. 3,4-亚甲二氧基硝基苯中所有原子位于同一平面上,其中O(1)最大偏离为-0.003 4 nm.
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| 关 键 词： | 3 4-亚甲二氧基硝基苯 合成 晶体结构 |
| 文章编号： | 1000-8608（2006）04-0488-03 |
| 收稿时间： | 2005-01-20 |
| 修稿时间： | 2005-01-202006-03-25 |
Synthesis and crystal structure of 3,4-methylenedioxy-nitrobenzene |
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| FENG Bai-cheng,HAN De-zhang,WU Zu-wang,WU Zuo-lin.Synthesis and crystal structure of 3,4-methylenedioxy-nitrobenzene[J].Journal of Dalian University of Technology,2006,46(4):488-490. |
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| Authors: | FENG Bai-cheng HAN De-zhang WU Zu-wang WU Zuo-lin |
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| Abstract: | 3,4-methylenedioxy-nitrobenzene was synthesized from 1,2-methylenedioxy-benzene by nitration. The structure of the compound was determined by X-ray crystallography. It is monoclinic, space group P21/c, Z=4. The lattice parameters of compound are as follows: a=0.378 00(8) nm; b=1.000 3(2) nm; c=1.822 4(4) nm; β=97.33(3)°; Mr=167.12; V=0.683 4(2) nm3, Dc=1.624 g/cm3, μ(MoKα)=0.136 mm-1, F(000)=344, R=0.070 7, wR=0.182 8. All atoms are to be coplanar with the maximum deviation of -0.003 4 nm for O(1). |
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| Keywords: | 3 4-methylenedioxy-nitrobenzene synthesis crystal structure |
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