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福建无烟粉煤和纸浆黑液水蒸气催化气化动力学研究
引用本文:钟雪晴,林驹.福建无烟粉煤和纸浆黑液水蒸气催化气化动力学研究[J].福州大学学报(自然科学版),2007,35(6):931-935.
作者姓名:钟雪晴  林驹
作者单位:福州大学化学化工学院,福建,福州,350002
基金项目:国家自然科学基金资助项目(20376014)
摘    要:在常压热分析仪上,运用等温法进行福建无烟粉煤和纸浆黑液水蒸气催化气化动力学研究实验,考察了温度和催化剂加载浓度的变化对碳转化率和气化反应速率的影响,并对催化气化动力学参数进行计算.实验结果表明:气化温度的升高和催化剂浓度的增大能显著提高炭转化率和气化速度.在本实验条件下,催化剂的饱和加载浓度为8%.

关 键 词:无烟煤  水蒸气  催化气化  动力学  福建
文章编号:1000-2243(2007)06-0931-05
修稿时间:2007年3月14日

Study on kinetics of catalytic gasification of Fujian anthracite and black liquor
ZHONG Xue-qing,LIN Ju.Study on kinetics of catalytic gasification of Fujian anthracite and black liquor[J].Journal of Fuzhou University(Natural Science Edition),2007,35(6):931-935.
Authors:ZHONG Xue-qing  LIN Ju
Institution:(College of Chemistry and Chemical Engineering,Fuzhou University,Fuzhou,Fujian,350002,China)
Abstract:A series of catalytic gasification tests of Fujian anthracite and black liquor with steam were performed in a thermo-gravimetric analyzer with isothermal thermo-gravimetric method in the conditions of different temperatures and catalyst concentrations.The effects of temperatures and catalyst concentrations on the carbon conversions and gasification rates were investigated,and the kinetic parameters were calculated.The results showed that carbon conversions and gasification rates increased with the increasing of gasification temperatures and catalyst concentrations.The catalyst loading saturation was found to be 8% by weight.
Keywords:coal  water steam  catalytic-gasification  kinetics  Fujian
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