| 非水溶液盐效应的静电作用研究 |
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| 引用本文： | 白同春,卢锦梭.非水溶液盐效应的静电作用研究[J].河南师范大学学报(自然科学版),1989(2):27-30. |
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| 作者姓名： | 白同春 卢锦梭 |
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| 作者单位： | 河南师范大学化学系
(白同春)，河南师范大学化学系(卢锦梭) |
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| 摘 要： | 本文应用B.E.Conway等的静电盐效应理论计算了各种质子型和非质子型非电解质溶质在环丁砜+盐溶液中的盐效应常数。讨论了不同类型溶质和电解质相互作用的差别。结果表明:用单纯的静电模型描述离子与质子型溶质的相互作用是不全面的。
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| 关 键 词： | 盐效应 非水溶液 静电作用 环丁砜 质子溶剂 非质子溶剂 |
THE STUDY OF SALT EFFECTS IN NONAQUEOUS SOLUTION BY ELECTROSTATIC INTERACTION |
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| Bai Tongchun,Lu Jinsuo.THE STUDY OF SALT EFFECTS IN NONAQUEOUS SOLUTION BY ELECTROSTATIC INTERACTION[J].Journal of Henan Normal University(Natural Science),1989(2):27-30. |
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| Authors: | Bai Tongchun Lu Jinsuo |
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| Institution: | Bai Tongchun;Lu Jinsuo |
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| Abstract: | Salt effects coeffioients of various protic and aprotic nonelectrolyte solute were calculated by usingConway's electrostatic theory. The difference of ion-solute interaction between different type of soluteswas discussed. The results shown: it is not correct to discribe the behavior of ion-protic solute interac-tion by electrostatic model alone. |
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| Keywords: | salt effect nonaqueous solution electrostatic interaction sulfolane protic solvents aprotic solvents |
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