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高比表面积石墨相氮化碳的制备及其光催化应用研究进展
引用本文:牛金叶,谢艺,王璐瑶,王谦,张永奎,王雅博. 高比表面积石墨相氮化碳的制备及其光催化应用研究进展[J]. 四川大学学报(自然科学版), 2018, 55(5): 1067-1077
作者姓名:牛金叶  谢艺  王璐瑶  王谦  张永奎  王雅博
作者单位:四川大学,四川大学,四川大学,四川大学,四川大学,四川大学
摘    要:石墨相氮化碳(g-C3N4)具有较好的物理化学稳定性,合适的能带结构,良好的可见光吸收性能,因而在光催化领域得到了广泛关注。作为异相催化剂,高比表面积可以提供较多的反应位点,增加反应物的接触,改善传质,从而促进催化性能的提升。本文综述了高比表面积g-C3N4的合成方法,介绍了两种增加g-C3N4比表面积的途径:(1)模板法制备多孔g-C3N4;(2)剥离法制备薄层g-C3N4纳米片。本文对高比面积g-C3N4的光催化应用也做了相应的介绍,并对g-C3N4的发展前景做了展望。

关 键 词:氮化碳;模板;剥离;高比表面积;光催化
收稿时间:2017-08-29
修稿时间:2017-10-29

Progress on the synthesis and photocatalytic applications of graphitic carbon nitride with high surface area
NIU Jin-Ye,XIE Yi,WANG Lu-Yao,WANG Qian,ZHANG Yong-Kui and WANG Ya-Bo. Progress on the synthesis and photocatalytic applications of graphitic carbon nitride with high surface area[J]. Journal of Sichuan University (Natural Science Edition), 2018, 55(5): 1067-1077
Authors:NIU Jin-Ye  XIE Yi  WANG Lu-Yao  WANG Qian  ZHANG Yong-Kui  WANG Ya-Bo
Affiliation:Sichuan University,Sichuan University,Sichuan University,Sichuan University,Sichuan University,Sichuan University
Abstract:Graphitic carbon nitride (g-C3N4) possesses good physical and chemical stability, suitable band structure and efficient visible light response, which has attracted numerous attention for photocatalytic applications. As heterogeneous catalyst, high surface area can provide abundant reaction sites, increase contact between reactants and catalyst, and enhance mass transfer, which are beneficial for catalytic efficiency enhancement. This review focuses on the preparation and photocatalytic applications of g-C3N4 with high surface area. Two major strategies are reviewed, which are template method for porous g-C3N4 preparation and exfoliation for thin-layer g-C3N4 nanosheet preparation. In addition, the photocatalytic applications of g-C3N4 are introduced. Finally, the prospective of g-C3N4 is described.
Keywords:g-C3N4   Template   Exfoliation   High surface area   Photocatalysis
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