| 微波消解-ICP—MS法测定黄土中的稀土元素 |
| |
| 引用本文： | 贾丽敏,陈秀玲.微波消解-ICP—MS法测定黄土中的稀土元素[J].海南师范大学学报(自然科学版),2013,26(1):71-74. |
| |
| 作者姓名： | 贾丽敏 陈秀玲 |
| |
| 作者单位： | 福建省湿润亚热带山地生态省部共建国家重点实验室培育基地,福建师范大学地理科学学院,福建福州350007 |
| |
| 基金项目： | 福建省自然科学基金资助项目 |
| |
| 摘 要： | 运用微波消解-ICP-MS法建立了一种测定黄土中稀土元素的新方法．用HNO3-HCl-HF三酸混合对样品进行微波消解，并加入HCIO4赶酸使样品完全溶解，以铟（1aSln）和铹（mRe）作为在线内标元素同步测定，减少基体效应对稀土元素的干扰，确定了最适宜的测定条件．分析了国家黄土标准土壤物质中的稀土元素，测定结果符合国家标准值的范围，线性相关系数均在0．9994以上，RSD％〈5．2，检出限为0．010-0．080．该方法有精确、快捷、可靠等，适用于新建伊犁盆地黄土样品的测定．
|
| 关 键 词： | 黄土 稀土元素 微波消解 ICP-MS |
Determination of Rare Earth Elements in the Loess by the ICP-MS and Microwave Digestion |
| |
| JIA Limin
,
CHEN Xiulin.Determination of Rare Earth Elements in the Loess by the ICP-MS and Microwave Digestion[J].Journal of Hainan Normal University:Natural Science,2013,26(1):71-74. |
| |
| Authors: | JIA Limin CHEN Xiulin |
| |
| Institution: | JIA Limin, CHEN Xiulin (College of Geographical Sciences, Fujian Normal University, Fujian Key Laboratory of Subtropical Resources and Environment,Fuzhou 350007,China) |
| |
| Abstract: | A new method to determinate rare earth elements in the loess by using microwave digestion （ICP-MS）is es- tablished. The sample is microwave digested directly with HNO3-HC1-HF, then adding HC104 to make sure the sample is completely dissolved. The matrix effect can be eliminated by selecting indium （HSIn） and rhodium （lSSRe） as online in- ternal standard elements to measure simultaneously. The results of the analysis of rare earth elements of standard soil in the loess of the country, with the linear correlation coefficient above 0.9994, RSD% 〈5.2, the detection limit of 0.010 to 0.080, are in line with national standards. With the satisfying results, the method can be used to determinate the loess samples of newly built Yili Basin based on its accurate, fast, and reliable characteristics. |
| |
| Keywords: | loess rare Earth Elements microwave digestion ICP-MS |
| 本文献已被 维普 万方数据 等数据库收录！ |
|
