Study on the reaction mechanism of naphthalene with oxalyl chloride |
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Authors: | Wu Lin Qin Yi-min Huang Bo Zong Zhi-ming Wei Xian-yong Chen Qing-ru Zou Guo-lin |
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Institution: | (1) College of Life Sciences, Wuhan University, 430072 Wuhan, China;(2) College of Chemical Engineering, China University of Mining & Technology, 221008 Xuzhou, China |
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Abstract: | The reaction of naphthalene with oxalyl chloride in the presence of anhydrous AlCl3 was investigated. The homolog of dinaphthyl methanone can be obtained mainly from this reaction. Naphthalene conversion does
not have evident correlation with the amount of AlCl3. The results show that the reaction proceeds via carbon cation electrophilic substitution reaction-free radical substitution
reaction pathway.
Foundation item: Supported by the National Nature Science Foundation of China (29676045)
Biography: Wu Lin(1965-), male, Postdocter, research direction: PAHs catalytic conversion and its biologic toxicity. |
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Keywords: | naphthalene oxalyl chloride carboncation free radical reaction mechanism |
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