| 聚合物支载的硼氢阴离子树脂还原某些含氮化合物生成胺的研究 |
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| 引用本文： | 杨桂春 陈家威. 聚合物支载的硼氢阴离子树脂还原某些含氮化合物生成胺的研究[J]. 湖北大学学报(自然科学版), 1997, 19(1): 53-55 |
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| 作者姓名： | 杨桂春 陈家威 |
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| 作者单位： | 湖北大学化学系 |
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| 摘 要： | 探讨了聚合物支载的硼氢阴离子在主族金属离子如Ｂｉ＾３＋和Ｓｂ＾３＋催化下，对一些含氮功能基化合物还原的研究，并对影响该反应的条件如温度，溶剂进行了讨论，发现它具有良好的还原选择性，并具有良好的还原效果。
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| 关 键 词： | 聚合物支载 硼氢阴离子树脂 还原 含氮化合物 胺 |
REDUCTION OF SOME NITROGENOUS FUNCTION GROUP COMPOUNDS WITH POLYMERSUPPORTED BOROHYDRIDE ANION RESIN |
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| Yang Guichun Chen Jiawei. REDUCTION OF SOME NITROGENOUS FUNCTION GROUP COMPOUNDS WITH POLYMERSUPPORTED BOROHYDRIDE ANION RESIN[J]. Journal of Hubei University(Natural Science Edition), 1997, 19(1): 53-55 |
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| Authors: | Yang Guichun Chen Jiawei |
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| Abstract: | Some nitrogenous functional groups, such as nitro, cyano and diazo compounds were reduced by using the polymersupported borohydride resin under the catalysis of some main group metal salts such as Bi 3+ and Sb 3+ . The effects of the reaction temperature and solvent on reducing reaction were also investigated. It had well reducing selectivity and good effect of reducing. |
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| Keywords: | Polymersupported borohydride anion resin Reduction Compornds of nitrogenious functional groups |
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