| 碱性氮化物对分子筛裂化催化剂失活动力学函数的考察 |
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| 引用本文： | 季宁秀,严正泽,朱钟敏,翁惠新,刘馥英. 碱性氮化物对分子筛裂化催化剂失活动力学函数的考察[J]. 华东理工大学学报(自然科学版), 1986, 0(5) |
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| 作者姓名： | 季宁秀 严正泽 朱钟敏 翁惠新 刘馥英 |
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| 作者单位： | 华东化工学院能源化工系(季宁秀，严正泽，朱钟敏，翁惠新)，华东化工学院能源化工系(刘馥英) |
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| 摘 要： | 本文用国产742#大孔强酸性离子交换树脂对胜利直馏柴油中的碱性氮化物进行了分离和分析。求出了在国产CRC-1分子筛裂化催化剂上轻燃料油反应网络的反应速率常数,並求得2-乙基呲啶、异喹啉、8-羟基喹啉这三种碱性氮化物在催化剂上的吸附常数,分别为45.56、37.00、23.40(克碱性氮/克催化剂)。实际柴油中的碱氮吸附常数是42。
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| 关 键 词： | 沸石 催化裂化 氮化食物 活化 动力学 |
The kinetic study of the deactivation effect of basic nitrogen compounds on the zeolite catalyst in the light fuel oil cracking |
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| Ji Ningxiu,Yan Zhengze,Zhu Zhongmin,Weng Huixin Liu Fuyin. The kinetic study of the deactivation effect of basic nitrogen compounds on the zeolite catalyst in the light fuel oil cracking[J]. Journal of East China University of Science and Technology, 1986, 0(5) |
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| Authors: | Ji Ningxiu Yan Zhengze Zhu Zhongmin Weng Huixin Liu Fuyin |
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| Affiliation: | Department of Chemical Engineering of Energy Sources |
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| Abstract: | By No. 742 resin, a domestic product of macroporous cation exchanger, the basic nitrogen compounds, a catalyst poison, were isolated from shengli straight-run gas oil, and the analyses concerned were made. A set of rate constants and adsorption coefficients of certain nitrogen compounds on CRC-1 molecular sieve for light fuel oil cracking network has also been obtained. The respective coefficients of 2-ethyl pyridine, isoquinoline and 8-hydroxyquinoline are 45.46, 37.00 and 23.40 (g basic nitrogen/g catalyst)~(-1). But the real adsorption coefficient of the basic nitrogen compounds present is actually 42. |
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| Keywords: | zeolite catalytic cracking nitrogen compounds activation dynamics |
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