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金属离子活化过硫酸钠降解靛蓝胭脂红的研究
引用本文:赵子叶,王磊,邵磊.金属离子活化过硫酸钠降解靛蓝胭脂红的研究[J].北京化工大学学报(自然科学版),2018,45(6):1-5.
作者姓名:赵子叶  王磊  邵磊
作者单位:北京化工大学化学工程学院有机无机复合材料国家重点实验室,北京 100029;北京化工大学教育部超重力工程研究中心,北京 100029;北京化工大学化学工程学院有机无机复合材料国家重点实验室,北京 100029;北京化工大学教育部超重力工程研究中心,北京 100029;北京化工大学化学工程学院有机无机复合材料国家重点实验室,北京 100029;北京化工大学教育部超重力工程研究中心,北京 100029
摘    要:以搅拌釜为反应装置,直接染料靛蓝胭脂红(IC)为目标污染物模拟染料废水,比较了Mn2+、Fe2+、Cu2+、Zn2+、Ag+、Mg2+ 6种金属离子活化过硫酸钠降解IC的效果。研究结果表明Fe2+对过硫酸钠的活化效果最好。通过对Fe2+活化过硫酸钠处理IC的条件进行优化发现,当温度为25℃、pH为7.3、IC质量浓度为200 mg/L、Na2S2O8浓度为0.8 mmol/L、Fe2+的浓度为0.8 mmol/L时,靛蓝胭脂红的脱色率可在5 min内达到100%。

关 键 词:过硫酸钠  金属离子活化  靛蓝胭脂红  脱色
收稿时间:2018-01-09

Decolorization of indigo carmine with sodium persulfate activated by metallic ions
ZHAO ZiYe,WANG Lei,SHAO Lei.Decolorization of indigo carmine with sodium persulfate activated by metallic ions[J].Journal of Beijing University of Chemical Technology,2018,45(6):1-5.
Authors:ZHAO ZiYe  WANG Lei  SHAO Lei
Institution:1. State Key Laboratory of Organic-Inorganic Composites, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China;2. Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing 100029, China
Abstract:The effect of Mn2+, Fe2+, Cu2+, Zn2+, Ag+, Mg2+ on the activation of sodium persulfate (PS) for the degradation of indigo carmine (IC) in a stirred tank reactor has been investigated. The experimental results showed that Fe2+ had the best activation effect on PS. The conditions of IC degradation by PS activated with Fe2+ were investigated and it was found that the decolorization efficiency of the simulated IC dye wastewater reached 100% in 5 min when the temperature, pH, IC concentration, PS concentration and Fe2+ concentration were 25℃, 7.3, 200 mg/L, 0.8 mmol/L and 0.8 mmol/L respectively.
Keywords:sodium persulfate                                                                                                                        metal ion activation                                                                                                                        indigo carmine                                                                                                                        decolorization
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