钙硅氧化物的质量比对10%Al2 O3高炉渣--尾矿--粉煤灰微晶玻璃性能的影响

利用高炉渣、尾矿和粉煤灰各自成分特点,在未添加任何晶核剂和其他化学试剂条件下,使用烧结法制得了不同CaO/SiO2质量比的10%Al2 O3(质量分数)矿渣微晶玻璃.通过差热分析、X射线衍射、扫描电子显微镜等分析手段,分析了CaO/SiO2质量比和析晶温度对高炉渣-尾矿-粉煤灰微晶玻璃样品的晶相变化规律、析晶行为和主要力学性能的影响.随着CaO/SiO2质量比增大,析晶活化能不断减小,Si-O四面体连接强度下降,质点移动加强,各组开始析晶温度和晶化温度逐渐减小.当玻璃样品中钙硅氧化物的质量比为0.4时,分别在886℃和982℃形核、析晶保温1 h 后,可以得到抗折强度103.59 MPa、显微硬度5.3 GPa、耐酸性0.25%(质量损失率)、耐碱性小于0.1%,主晶相为透辉石的最佳力学性能的微晶玻璃样品.

Effect of CaO/SiO2 mass ratio on the properties of glass ceramics containing 10% Al2 O3 from blast furnace slag,tailing and coal fly ash

ABSTRACT Blast furnace slag, tailing and coal fly ash were used as starting materials for preparing glass-ceramics by the sintering method based on their characteristics and without adding any other nucleating and chemical agents. The effects of CaO/SiO2 mass ratio and crystallization temperature on the crystaltransition, crystallization behavior and main mechanical properties of slag glass-ceramics with 10% Al2 O3 were systematically investigated by differential thermal analysis, X-ray diffraction and scanning electron microscopy. When the CaO/SiO2 mass ratio increases, the crystallization activation energy decreases, the Si—O tetrahedral bonding strength de-creases, the particle movement strengthens, and the crystallization onset temperature and the crystallization temperature decrease. The glass samples with a CaO/SiO2 mass ratio of 0.4, sintered at 886℃ for 1 h as a nucleation process and at 982℃ for 1 h as a crystalli-zation process, possess the best performance with the bending strength of 103.59 MPa, the microhardness of 5.3 GPa and the acid and alkali resistances of 0.25% and<0.1% ( mass loss rate) respectively. Moreover, the major phase of the glass ceramics is diopside.