Zur Stereochemie der Propandioldehydrase-Reaktion |
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| Authors: | J. Rétey A. Umani-Ronchi D. Arigoni |
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| Affiliation: | (1) Organisch-chemisches Laboratorium, Eidgenössische Technische Hochschule, Zürich, Schweiz |
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| Abstract: | Summary Propanedioldehydrase is shown to convert both (+)-(S)-2-2H-propanediol,3, and (–)-(R)-1-2H2-propanediol,5, to specimens of deuterated propion-aldehyde, for which the (S)-configuration has been established. Thus, in the propanedioldehydrase reaction migration of hydrogen atoms from C–1 to C–2 always occurs with inversion of configuration. |
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