| ^13C化学位移与不对称烯烃的亲电加成 |
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| 引用本文： | 王进贤,席永盛.^13C化学位移与不对称烯烃的亲电加成[J].西北师范大学学报,1997,33(2):97-99. |
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| 作者姓名： | 王进贤 席永盛 |
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| 作者单位： | 西北师范大学化学系 |
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| 摘 要： | 根据单取代苯１３Ｃ核磁化学位移所计算的电子效应值，结合可极化率观点，解释并定量判断不对称烯烃的亲电加成定位
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| 关 键 词： | ~(13)C化学位移 电子效应 可极化率 烯烃 加成定位 |
Carbon 13 chemical shift and the eletrophilic addition of asymmetric olefins |
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| Wang,Jinxian,Xi,Yongsheng,Du,Zhengyin.Carbon 13 chemical shift and the eletrophilic addition of asymmetric olefins[J].Journal of Northwest Normal University Natural Science (Bimonthly),1997,33(2):97-99. |
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| Authors: | Wang Jinxian Xi Yongsheng Du Zhengyin |
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| Abstract: | The addition orientation of asymmetric substituted olefins can be claimed and determined,according to the value of eletron effect calculated by carbon 13 NMR chemical shift of monosubstituted benzene and polarizable character.This method is more direct and quantitative than conventional ones. |
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| Keywords: | carbon 13 chemical shiftelectron effectpolarizable characterolefinadd ition oriention |
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