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稳态光电压测量技术
引用本文:徐金杰,王献伟,王德军,张兴堂,黄亚彬,杜祖亮,李铁津.稳态光电压测量技术[J].河南大学学报(自然科学版),2005,35(3):15-18.
作者姓名:徐金杰  王献伟  王德军  张兴堂  黄亚彬  杜祖亮  李铁津
作者单位:吉林大学,化学学院,长春,130023;河南大学,特种材料重点实验室,河南,开封,475001
基金项目:国家重点基础研究发展规划(973)项目(2002CCC02700);国家自然科学基金项目(90306010:20371015)
摘    要:给出稳态光电压测量方法的原理图,比较MIS模式与夹层模式得到的SPV信号,结合光电流响应的测量,以金红石型TiO2(001)面单晶表面为研究对象,可以看出夹层模式与MIS模式得到的光电压结果近似,夹层模式具有更高的灵敏度,结合弱场诱导夹层模式能够给出更多的亚带隙跃迁的信息,而外加电场对光电流和MIS模式测得的光电压没有影响.同时比较有无弱场存在时的SPV与光电流信号,探讨了弱场诱导的可能作用机理.亚带隙跃迁得到的光电压具有与高于带隙宽度的光电压响应不同的产生机制和电荷分离模式。

关 键 词:稳态光电压  光电流  电场诱导  亚带隙跃迁  TiO2
文章编号:1003-4978(2005)03-0015-04
收稿时间:2005-02-16
修稿时间:2005年2月16日

Steady-State Surface Photovoltage Technique
XU Jin-jie,WAND Xian-wei,WANG De-jun,ZHANG Xing-tang,HUANG Ya-bin,DU Zu-Liang,LI Tie-jin.Steady-State Surface Photovoltage Technique[J].Journal of Henan University(Natural Science),2005,35(3):15-18.
Authors:XU Jin-jie  WAND Xian-wei  WANG De-jun  ZHANG Xing-tang  HUANG Ya-bin  DU Zu-Liang  LI Tie-jin
Abstract:Combined with the equivalent circuit diagram and principle sketch map of steady-state SPV measurement, the SPV values of c-axis TiO2 single crystal are estimated and compared with the value estimated from photocurrent measurement. The SPV values are obtained by the sandwich SPV measurement model and the MIS SPV measurement model. The experiment shows that the sandwich SPV measurement model is similar to MIS SPV measurement model and has higher sensitivity. Furthermore, the sandwich model can provide sub-gap transition SPV information when biasing a weak dc field. And the weak dc field is of no effect on MIS model SPV and photocurrent signal, The weak dc field works in localized state transition and can not affect delocalized transition. On the other hand, the sub-gap transition SPV has different carrier separating mechanism from super-gap transition SPV.
Keywords:steady-state surface photovoltage  photocurrent  field-induced effect  sub-gap transition  TiO2
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