| LB型中温变换催化剂本征动力学研究 |
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| 引用本文： | 张力峰,李建伟,陈标华.LB型中温变换催化剂本征动力学研究[J].北京化工大学学报(自然科学版),2004,31(1):6-10,14. |
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| 作者姓名： | 张力峰 李建伟 陈标华 |
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| 作者单位： | 北京燕山石油化工股份有限公司化学品事业部,北京,102500;北京化工大学可控化学反应科学与技术基础教育部重点实验室,北京,100029 |
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| 摘 要： | 在3 MPa,598～728 K和反应器入口气体组成(摩尔分数)CO 0.066～0.139，CO2 0.041～0.1，H20.262～0.457，H2O 0.217～0.386，N2 0.077～0.271，余为CH4条件下，采用微型等温积分反应器,对低汽-气摩尔比LB型一氧化碳中温变换催化剂的本征反应特性进行了实验研究。以复合型法对实验数据进行非线性参数估值，建立了能良好吻合实验数据的幂函数型LB中温变换催化剂加压本征动力学模型。工业检验结果进一步表明，该动力学模型的应用是安全和可靠的。
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| 关 键 词： | 动力学 中温变换催化剂 一氧化碳变换 |
| 收稿时间： | 2003-07-11 |
| 修稿时间： | 2003年7月11日 |
Intrinsic kinetics of LB catalyst for water-gas shift reaction |
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| Zhang Li-feng,Li Jian-wei,Chen Biao-hua.Intrinsic kinetics of LB catalyst for water-gas shift reaction[J].Journal of Beijing University of Chemical Technology,2004,31(1):6-10,14. |
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| Authors: | Zhang Li-feng Li Jian-wei Chen Biao-hua |
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| Institution: | 1.Yanshan Petrochemical Corporation, Beijing; 2.The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education,Beijing University of Chemical Technology, China |
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| Abstract: | The intrinsic kinetic experiments of water-gas shift reaction over a domestic catalyst of LB type were carried out in an integral micro-reactor under following conditions: 3MPa, 598～728K, and feed gas composition (mole fraction) CO 0.066～0.139, CO2 0.041～0.1, H2 0.262～0.457, H2O 0.217～0.386 and N2 0.077～0.271. A kinetic model of power-law type was developed, and the kinetic model parameters were estimated by means of complex method. The results of statistical and industrial application tests show that this model is high acceptable and reliable. |
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| Keywords: | kinetics high temperature shift catalyst carbon monoxide shift reaction |
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