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基于Langmuir理论的平衡吸附量预测模型
引用本文:张志军,刘炯天,冯莉,邹文杰.基于Langmuir理论的平衡吸附量预测模型[J].东北大学学报(自然科学版),2011,32(5):749.
作者姓名:张志军  刘炯天  冯莉  邹文杰
作者单位:张志军,ZHANG Zhi-jun(东北大学,资源与土木工程学院,辽宁沈阳,110819);刘炯天,LIU Jiong-tian(东北大学,资源与土木工程学院,辽宁沈阳,110819;中国矿业大学,化工学院,江苏徐州,221008);冯莉,邹文杰,FENG Li,ZOU Wen-jie(中国矿业大学,化工学院,江苏徐州,221008)
基金项目:教育部科学研究重大项目,创新学者攀登计划项目,中央高校基本科研业务费专项资金资助项目
摘    要:为了实现对吸附反应的平衡吸附量的预测,建立了平衡吸附量预测模型.以高岭土、蒙脱土这两种黏土矿物吸附Ca2+为例,验证其等温吸附曲线符合Langmuir吸附方程.在Langmuir吸附等温式的基础上,建立了平衡吸附量预测模型,该模型应用于单组分吸附反应的平衡吸附量的预测.通过实验对该模型进行了验证,模型的计算结果与实验结果可以较好地吻合,证明该模型的可靠性较高.

关 键 词:吸附反应  Langmuir吸附等温式  平衡吸附量  预测模型  

A Prediction Model Based on Langmuir Theory for Equilibrium Adsorption Amount
ZHANG Zhi-jun,LIU Jiong-tian,FENG Li,ZOU Wen-jie.A Prediction Model Based on Langmuir Theory for Equilibrium Adsorption Amount[J].Journal of Northeastern University(Natural Science),2011,32(5):749.
Authors:ZHANG Zhi-jun  LIU Jiong-tian  FENG Li  ZOU Wen-jie
Institution:(1) School of Resources and Civil Engineering, Northeastern University, Shenyang 110819, China; (2) School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221008, China
Abstract:A model was developed to predict equilibrium adsorption amount in an adsorption reaction. The adsorption isotherm of kaolinite and montmorillonite adsorbing Ca2+ followed the Langmuir adsorption equation. Based on the Langmuir isothermal adsorption equation, a model was developed that is able to predict the equilibrium adsorption of single component adsorption reactions. Results calculated by the prediction model coincided with experimental results, indicating good reliability of the prediction model.
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