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配合物{[Zn(HFlu)2(CHO2)]·NO3}n的合成、表征及其晶体结构
引用本文:王代银,罗伟强,汤金牛,安永鹏.配合物{[Zn(HFlu)2(CHO2)]·NO3}n的合成、表征及其晶体结构[J].广西民族学院学报(自然科学版),2012(1):84-87.
作者姓名:王代银  罗伟强  汤金牛  安永鹏
作者单位:广西民族大学化学化工学院,广西南宁530006
基金项目:广西自然科学基金(0832080); 广西民族大学研究生教育创新计划项目(gxun-chx2011085)
摘    要:用水热合成法以硝酸锌、氟康唑(HFlu)、甲酸为原料合成了一种新颖的配合物,利用单晶X射线、元素分析、等对配合物进行了表征.单晶X射线衍射分析的结果表明:标题化合物属于三斜晶系,空间群为P-1,晶胞参数为a=10.503(10),b=11.745(11),c=14.122(13),α=90.808(11),β=105.841(11),γ=101.996(11).锌采用六配位的模式,且位于变形的八面体中心,每个锌原子分别与4个各异氟康唑上的三氮唑Zn-N=2,156(2)]的4-号氮原子以及两个甲酸根Zn-O=2.086(2)或者是2.137(5)]进行配位.

关 键 词:晶体结构  氟康唑    配位聚合物

Synthesis,Characterization,Crystal Structure of a New Zinc(Ⅱ) Coordination Complexes of Fluconazol
WANG Dai-yin,LUO Wei-qiang,TANG Jin-niu,AN Yong-peng.Synthesis,Characterization,Crystal Structure of a New Zinc(Ⅱ) Coordination Complexes of Fluconazol[J].Journal of Guangxi University For Nationalities(Natural Science Edition),2012(1):84-87.
Authors:WANG Dai-yin  LUO Wei-qiang  TANG Jin-niu  AN Yong-peng
Institution:(College of Chemistry and Chemical Engineering,Guangxi University for Nationalities,Nanning 530006,China)
Abstract:A coordination polymer containing divalent zinc,fluconazole,formic acid radical has been obtained by hydrothermal method.Its structure was determined by means of single-crystal X-ray diffraction analysis with the following crystal data:triclinic space group P-1,a = 10.503(10) ,b = 11.745(11) ,c= 14.122(13) ,α= 90.808(11) ,β= 105.841(11) ,γ= 101.996(11) .The mode of Zinc was Six coordination and located the center of distortion octahedral,Each zinc center was coordinated to four triazole nitrogenZn-N=2,156(2) ] atoms from distinct fluconazole ligands and a pair of formic acid radicalZn-O=2.086(2)  or.137(5) ].
Keywords:crystal structure  fluconazole  Zinc  coordination polymer
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