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高纯铝箔在混合酸溶液中蚀孔的引发和生长机理
引用本文:徐友龙,孟中岩.高纯铝箔在混合酸溶液中蚀孔的引发和生长机理[J].西安交通大学学报,1997,31(1):1-6.
作者姓名:徐友龙  孟中岩
作者单位:西安交通大学,上海大学
摘    要:通过恒电流实验研究了高纯铝箔在混合酸溶液中不同腐蚀时间时的试样表面形貌,探讨了蚀孔的引发和生长过程.对腐蚀区和未腐蚀区进行EDAX微量元素分析,初步提出蚀孔的引发和生长控制模型,合理地解释了恒电流实验的结果

关 键 词:电解电容器  高纯铝箔  蚀孔的引发和生长

The Initiation And Growth Mechanism of Etchpit for High Purity Aluminum Foil in Mixed Acid Solutions
Xu,Youlong,Cao,Wanzhen.The Initiation And Growth Mechanism of Etchpit for High Purity Aluminum Foil in Mixed Acid Solutions[J].Journal of Xi'an Jiaotong University,1997,31(1):1-6.
Authors:Xu  Youlong  Cao  Wanzhen
Abstract:The high purity aluminum foils are galvanostatically etched in an aqueous solution of hydrochloric acid, sulfuric acid, sodium dichromate and hydrofluoric acid. The morphology of the foil surface within different etching time observed by SEM shows that the etchpits are in a cluster during the first thirty seconds and then uniformly distributed over subsequent thirty seconds. The elements detected by EDAX reveal that the content of Cu, Fe and Cr in etched region is obviously greater than that in an unetched region where the Cu and Fe are segregated from the foils as the impurity and the Cr is induced from forming conversion coating. The conversion coating controlled model for initiation and growth of etchpits is proposed.
Keywords:electrolytic  capacitor  high  purity  aluminum  foil  initiation  and  growth  of  etchpit  
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