紫外分光光度法用于三峡库区水体总氮的测定

水体富营养化将破坏生态环境平衡．衡量水体是否发生富营养化污染的一个重要评价指标，是准确测定水体中总氮的含量．三峡库区筑坝后，水体流速减缓，可能导致水体富营养化污染的发生．依据朗伯一比尔定律，采用碱性过硫酸钾消解、紫外分光光度法，开展了三峡库区水体中总氮含量的测定工作．研究分析了影响总氮精确测定的各种可能因素，提出并改进了适合于实验室环境条件，也能获得高准确度结果的总氮测定方法．采用改进后的紫外分光光度法，对三峡库区内重庆主城区的嘉陵江实际水样中的总氮含量进行了测定与分析．研究结果表明，测得水样的总氮含量为0．6～1．0mg／L，小于国家规定的发生富营养化污染的限定值（≥2．0mg／L），得出三峡库区水体尚未发生富营养化污染的结论．

Applicationg of Ultraviolet Spectrophometry to Determination of Total Nitrogen in the Three Gorges Reservior

The eutrophication of water body will destroy the balance of ecological environment.To determine the total nitrogen content in water body exactly,is one of the most important evaluating indicators that whether the water body has been polluted by eutrophication or not.After the foundation of the Three Gorges Reservoir,current velocity lowers and it may result in the eutrophication of water body.In terms of the Lambert-Beer Law,the authors adopt potassium sulpersulphate oxidation-ultraviolet spectrophotometry to determine the total nitrogen content in the Three Gorges Reservoir.By analyzing a variety of possible factors,they bring forward a method to determine the total nitrogen which can be used in lab and also have high performance.With this improved method,the authors determine the factual water samples of the Three Gorges Reservoir in the main urban area of Chongqing,and the result is that the total nitrogen content is(0.6~1.0) mg/L,less than the limiting value(2.0 mg/L) in national standard.So the water body of the Three Gorges Reservoir still eutrophication does not take place.So eutrophication does not take place in water body of the Three(Gorges) Reservior.