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MODIFIED OPAL:A NOVEL STABILIZER FOR HYDROGEN PEROXIDE BLEACHING OF PULPS
Authors:Xueren Qian  Xianhui An  Wenbo Liu  Gang YU  Zhanqian Song
Abstract:The possibility of modified opal as the stabilizer of hydrogen peroxide bleaching was investigated. The results showed that the modified opal in place of sodium silicate as the stabilizer of hydrogen peroxide bleaching is feasible. At the same dosage, above 3% ISO can be increased for both wheat straw pulp and deinked pulp. The stabilizing ability of the modified opal to hydrogen peroxide bleaching of pulp is improved markedly. It is favorable for bleaching to increase temperature and time within a permissive extent. The suitable process conditions are 10% of pulp consistency, 3% of hydrogen peroxide, 1.5% of sodium hydroxide, 3% of the modified opal, 70℃ and 60 min when the modified opal is used as the stabilizer of hydrogen peroxide bleaching. At these conditions, the brightness gain can reach about 16% ISO for wheat straw pulp. In addition, it is favorable for bleaching to add a little magnesium sulfate when the modified opal is used as the stabilizer of hydrogen peroxide bleaching, the brightness of pulp can increase I%ISO if0.05% of magnesium sulfate is added. The cost analysis indicated that the modified opal is superior to sodium silicate as the stabilizer of hydrogen peroxide bleaching in economical aspect and has further the potential of market development.
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