| 二氮杂萘联苯型聚芳醚聚合机理的探讨 |
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| 引用本文： | 蹇锡高,朱秀玲.二氮杂萘联苯型聚芳醚聚合机理的探讨[J].大连理工大学学报,1999,39(5):629-634. |
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| 作者姓名： | 蹇锡高 朱秀玲 |
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| 作者单位： | 大连理工大学高分子材料系!辽宁大连116012 |
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| 基金项目： | 国家“九五”重点科技攻关项目 |
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| 摘 要： | 以自制的类双酚化合物与二卤单体反应，以及类双酚与对氯苯腈反应合成了３种模型化合物；通过对模型化合物的结构分析，证实了该新型类双酚单体中Ｎ－Ｈ参与亲核取代反应，形成了Ｃ－Ｎ相连而非Ｃ－Ｏ相连结构，进而提出了类双酚单体经亲核取代反应合成聚芳醚的反应机理。
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| 关 键 词： | 聚芳醚 聚合 二氮杂萘联苯型 |
Study on polymerization mechanism of poly(aryl ether)s containing phthalazinone moieties |
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| JIAN Xi\|gao,ZHU Xiu\|ling,CHEN Lian\|zhou.Study on polymerization mechanism of poly(aryl ether)s containing phthalazinone moieties[J].Journal of Dalian University of Technology,1999,39(5):629-634. |
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| Authors: | JIAN Xi\|gao ZHU Xiu\|ling CHEN Lian\|zhou |
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| Abstract: | A novel phenol\|like compound 4\|phenyl\|2,3\|phthalazine\|1\|one and the bisphenol\|like monomer 4\|(4\|hydroxylphenyl)\|2,3\| phthalazine\|1\|one were successfully used to synthesize three model compounds to prove the polymerization mechanism. The structure of the model compounds implied the C N coupling reaction. By analysis of the model reaction, the polymerization mechanism of the monomer is put forward. |
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| Keywords: | polymerization mechanism/phenol\|like compound bisphenol\|like compound model compound |
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