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贵金属基初次固溶体的固溶度和晶体态电子浓度之间的关系
引用本文:萧功伟. 贵金属基初次固溶体的固溶度和晶体态电子浓度之间的关系[J]. 江西科学, 1988, 0(1)
作者姓名:萧功伟
作者单位:江西省科学院 南昌
摘    要:本文引用文献[1]中提出的晶体态电子浓度φ=N_e/N_α的概念,重新解释了贵金属基初次固溶体的固溶度问题,分析结果与预期结果基本上是一致的,消除了Hume-Rothery初次固溶体规则在解释这一问题上所出现的矛盾和分歧。

关 键 词:贵金属基  初次固溶体  固溶度  晶体态电子浓度  初次固溶体规则

THE CORRELATION BETWEEN THE SOLID SOLUBILITY OF THE PRIMARY SOLID SOLUTIONS BASED ON NOBLE METALS AND THE CRYSTALLINE ELECTRON CONCENTRATION
Xiao Gongwei. THE CORRELATION BETWEEN THE SOLID SOLUBILITY OF THE PRIMARY SOLID SOLUTIONS BASED ON NOBLE METALS AND THE CRYSTALLINE ELECTRON CONCENTRATION[J]. Jiangxi Science, 1988, 0(1)
Authors:Xiao Gongwei
Abstract:In this note, the conception of the crystalline electron concentration proposed in [1] was based as a background to estimate the solid solubility of the primary solid solutions based on noble metals. Works mentioned above suggested that the crystalline electron concentration might affect on the solid solubility significantly. Therefore this should be a correct way to approach this subject.
Keywords:Noble metals based   Primary solid solutions  Solid solubility   Crystalline electron concentration   Rule of primary solid solutions.  
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