| 胆甾液晶冠醚固定相的气相色谱性能研究 |
| |
| 引用本文： | 卿笑天 周在德. 胆甾液晶冠醚固定相的气相色谱性能研究[J]. 四川大学学报(自然科学版), 1997, 34(2): 212-215 |
| |
| 作者姓名： | 卿笑天 周在德 |
| |
| 作者单位： | [1]川北医学院化学教研室 [2]四川大学化学系 |
| |
| 摘 要： | ４‘－胆甾烯氧羰基苯并－１５－冠－５（ＣＨ－Ｂ－１５－Ｃ－５）在不同温度范围内其相态不同，在同一温度范围内因处理方式不同而物性亦相去甚远，用其作成了兼具气固色谱，普通气液色谱和冠醚液晶气液色谱多种性能的固定相。用该固定相在不同条件下，对脂肪烃，脂肪酸，羧酸乙以及多种有机混合物等进行了ＧＳＣ，ＧＬＣ和ＣＬ－ＧＬＣ分离，发现它对这些物质有较强的分离能力，均获得对称良好的色谱峰。
|
| 关 键 词： | 胆甾 液晶 冠醚 气相色谱 固定相 |
STUDIES ON CHROMATOGRAPHIC CHARACTERISTICS OF CHOLESTERIC MESOMORPHIC CROWN ETHER AS STATIONARY PHASE FOR GAS CHROMATOGRAPHY |
| |
| Qing Xiaotian. STUDIES ON CHROMATOGRAPHIC CHARACTERISTICS OF CHOLESTERIC MESOMORPHIC CROWN ETHER AS STATIONARY PHASE FOR GAS CHROMATOGRAPHY[J]. Journal of Sichuan University (Natural Science Edition), 1997, 34(2): 212-215 |
| |
| Authors: | Qing Xiaotian |
| |
| Abstract: | The chromatographic characteristics,such as,the chemical stability,thermal stability,polarity,selectivity and the allowable operating temperature range,of CH B 15 C 5 as stationary phase for GC were studied in this paper.The separations of C 1-C 6 alcohols,ethyl asters of C 1-C 8 carboxylic acid,C 5-C 12 n alkanes and the other organic compounds mixtures were carried on the column packed with CH B 15 C 5.The results of separation were satisfactory.A possible retention mechanism is proposed to explain retention behaviours of the substances. |
| |
| Keywords: | ? Cholestenoxycarbonyl benzo 15 crown 5 liquid crystalline crown ether gas chromatography stationary phase |
| 本文献已被 CNKI 维普 等数据库收录！ |
