| 硒催化CO/H_2O还原3,4-二氯硝基苯制3,4-二氯苯胺 |
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| 引用本文： | 张晓鹏,李德胜,孔令合,王岩,赵骁,刘会利.硒催化CO/H_2O还原3,4-二氯硝基苯制3,4-二氯苯胺[J].河南师范大学学报(自然科学版),2013,41(3):96-98. |
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| 作者姓名： | 张晓鹏 李德胜 孔令合 王岩 赵骁 刘会利 |
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| 作者单位： | 1. 河南师范大学化学化工学院;绿色化学介质与反应省部共建教育部重点实验室,河南新乡453007
2. 滑县枣村乡第一初级中学,河南滑县,450000 |
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| 基金项目： | 河南省教育厅科技攻关项目，河南师范大学青年骨干教师项目，河南师范大学大学生创新性实验计划项目 |
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| 摘 要： | 报道了一种绿色、经济、简易、高效的制备3,4-二氯苯胺的方法.以廉价易得的非金属硒作催化剂,用CO/H2O可将3,4-二氯硝基苯还原为3,4-二氯苯胺,在优化条件下,3,4-二氯硝基苯可完全转化,目标产物3,4-二氯苯胺的收率可达96%.
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| 关 键 词： | 硒催化 一氧化碳/水 3 4-二氯硝基苯 3 4-二氯苯胺 |
Selenium-catalyzed Reduction of 3, 4-Dichloronitrobenzene to 3, 4-Dichloroaniline with CO/H2O |
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| ZHANG Xiaopeng
,
LI Desheng
,
KONG Linghe
,
WANG Yan
,
ZHAO Xiao
,
LIU Huili.Selenium-catalyzed Reduction of 3, 4-Dichloronitrobenzene to 3, 4-Dichloroaniline with CO/H2O[J].Journal of Henan Normal University(Natural Science),2013,41(3):96-98. |
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| Authors: | ZHANG Xiaopeng LI Desheng KONG Linghe WANG Yan ZHAO Xiao LIU Huili |
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| Institution: | 1(1.School of Chemistry and Chemical Engineering;Key Laboratory of Green Chemical Media and Reactions,Ministry of Education, Henan Normal University,Xinxiang 453007,China;2.The First Junior Middle School of Zaocun,Huaxian 450000,China) |
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| Abstract: | A green,economical,facile and efficient approach to 3,4-dichloroaniline is reported.With cheap and easily available nonmetal selenium as catalyst,3,4-dichloronitrobenzene can be reduced to 3,4-dichloroaniline with CO/H2O.3,4-Dichloronitrobenzene can be converted completely and 3,4-dichloroaniline can be obtained in yield of 96% under the optimized reaction conditions. |
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| Keywords: | selenium-catalyzed CO/H2O 3 4-dichloronitrobenzene 3 4-dichloroaniline |
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