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盐,表面活性剂及温度对1,3—二(α—萘基)丙烷荧光的影响
引用本文:谢锐强 雷学工. 盐,表面活性剂及温度对1,3—二(α—萘基)丙烷荧光的影响[J]. 兰州大学学报(自然科学版), 1993, 29(3): 145-150
作者姓名:谢锐强 雷学工
作者单位:兰州大学化学系,兰州大学化学系,兰州大学化学系 兰州 730000,兰州 730000,兰州 730000
基金项目:国家自然科学基金,国家教委资助优秀青年教师基金
摘    要:

关 键 词:荧光 盐盐效应 温度效应 丙烷 綦基

Effects of Salt,Ionic Surfactants and Temperature on the Fluorescence Behavior of 1,3-di (1-naphthyl) Propane
Xie Ruiqiang Lei Xuegong Liu Youcheng. Effects of Salt,Ionic Surfactants and Temperature on the Fluorescence Behavior of 1,3-di (1-naphthyl) Propane[J]. Journal of Lanzhou University(Natural Science), 1993, 29(3): 145-150
Authors:Xie Ruiqiang Lei Xuegong Liu Youcheng
Affiliation:Xie Ruiqiang Lei Xuegong~* Liu Youcheng
Abstract:A study on the effects of salt,ionic surfactants (before their CMC) and temperature on the fluorescence behavior of 1,3-di (l-naphthyl)propane (1)in aqueous methanol binary solvent (V:V=1:1)has been performed. The higher polarity of the medium caused by the added salt(NaCl) is in favour of the formation of excimer. The viscosity and polarity of the medium can be increased by theadded SDS while CTAB acts only as a salt due to its alkyl chain coiling. The vibronic structures of excimer induced by the bases can be broken down with the increase of temperature. Higher temperature is favourable to the excimer. The temperature effect also provides a further evidence to the distinct interaction between land cyclodextrins.
Keywords:fluorescence  Salt effect  temperature effect  surfactant effect  1  3-di (1-haphthyl) propane.
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