| 导电高分子聚苯胺载铂电极的交流阻抗测定 |
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| 引用本文： | 孙书明,叶若芬,王文欣,崔维真,武克忠,王庆飞. 导电高分子聚苯胺载铂电极的交流阻抗测定[J]. 河北师范大学学报(自然科学版), 2007, 31(3): 345-348 |
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| 作者姓名： | 孙书明 叶若芬 王文欣 崔维真 武克忠 王庆飞 |
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| 作者单位： | 沧州职业技术学院,化工系,河北,沧州,061001;河北师范大学,化学与材料科学学院,河北,石家庄,050016 |
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| 摘 要： | 利用循环伏安方法电聚合导电高分子聚苯胺.用于在直接甲醇燃料电池电极中负载催化剂Pt.聚苯胺载Pt电极(Pt/PAni/C)的制备,提高了Pt的分散度,增加了Pt在电催化体系中的利用率.交流阻抗测试结果表明:Pt/PAni/C与直接碳载Pt电极(Pt/C)相比,电化学反应电阻减小,催化活性增高.通过比较Pt/PAni/C与Pt/C对甲醇的电催化氧化活性可知,Pt/PAni/C电极催化氧化甲醇的最大电流为50.7mA/cm2,是Pt/C电极最大氧化电流(7.6mA/cm2)的6.67倍.
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| 关 键 词： | 聚苯胺 交流阻抗 电催化氧化 |
| 文章编号： | 1000-5854(2007)03-0345-04 |
| 修稿时间： | 2006-09-21 |
Electrochemical Impedance Spectroscopy of Platinum Loaded onto Polyaniline Electrode |
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| SUN Shu-ming,YE Ruo-fen,WANG Wen-xin,CUI Wei-zhen,WU Ke-zhong,WANG Qing-fei. Electrochemical Impedance Spectroscopy of Platinum Loaded onto Polyaniline Electrode[J]. Journal of Hebei Normal University, 2007, 31(3): 345-348 |
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| Authors: | SUN Shu-ming YE Ruo-fen WANG Wen-xin CUI Wei-zhen WU Ke-zhong WANG Qing-fei |
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| Affiliation: | 1. Department of Chemical Engineering,Cangzhou Vocational College of Technology,Hebei Cangzhou 061001 ,China; 2. College of Chemistry and Material Sciences, Hebei Normal University, Hebei Shijiazhuang 050016, China |
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| Abstract: | Poyaniline is electropolymerized onto carbon paper to load Pt as electrode has been performanced by the cyclic voltammetric method.The polyaniline is found to have a significant bearing on the size of the platinum deposits,which may enable an increase in the level of platinum utilization currently achieved in these systems.The results of EIS confirm that the Pt/PAni/C electrode is not only higher catalyst activation but also lower charge-transfer resistance than the Pt/C electrode.The electroactivation of the methanol oxidized on carbon paper electrode(Pt/C) and onto polyaniline loading Pt electrode(Pt/PAni/C) are studied by cyclic voltammetry.The maximum oxidation current of methanol on Pt/PAni/C is 50.7 mA/cm2 which is 6.67 times higher than 7.6 mA/cm2 on the Pt/C. |
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| Keywords: | polyaniline EIS electrocatalytic oxidation |
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