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钙钛矿型铁电体铁电相变时介电表现
引用本文:王裕斌 孙清池. 钙钛矿型铁电体铁电相变时介电表现[J]. 天津大学学报(自然科学与工程技术版), 1994, 27(3): 300-304
作者姓名:王裕斌 孙清池
摘    要:铁电-铁电相变并不总是伴随介电峰值。BaTiO3出现峰值,PbZr1-xTixO3系统则不是,利用铁电热力学理论研究了出现介电峰值的条件,并将此与斜方相是否存在联系起来。

关 键 词:钙钛矿型 铁电体 相变 电容率

DIELECTRIC BEHAVIORS OF THE PEROVSKITE FERROELECTRICS AT FERROELECTRIC-FERROELECTRIC TRANSFORMATIONS
Wang Yubin, Sun Qingcki. DIELECTRIC BEHAVIORS OF THE PEROVSKITE FERROELECTRICS AT FERROELECTRIC-FERROELECTRIC TRANSFORMATIONS[J]. Journal of Tianjin University(Science and Technology), 1994, 27(3): 300-304
Authors:Wang Yubin   Sun Qingcki
Affiliation:Dept.of Materials Science and Engineering
Abstract:Morphotropic or polymorphic transformations between ferroelectric phases donot always involve a peak value in the dielectric constant.BaTiO3 generates a peak, but PZTdoes not.The thermodynamic theory of ferroelectrics is applied to study the condition for appearance of a dielectric constant peak at ferroelectric-ferroelectric transformati on.It is foundthat the condition is related to the stability of the orthorhombic phase.
Keywords:PZT ceramics  perovskite ferroelectrics  thermodynamic theory of ferroelectric  ferroelectric-ferroelectric phase transformation  
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